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CoS2-TiO2@C Core-Shell fibers as cathode host material for High-Performance Lithium-Sulfur batteries | |
Li, Dianming1; Li, Hongtai2; Zheng, Shumin2; Gao, Ning2; Li, Shuai1; Liu, Jing1; Hou, Lanlan1; Liu, Jingchong1; Miao, Beibei3; Bai, Jie3; Cui, Zhimin1; Wang, Nu1; Wang, Bao2; Zhao, Yong1 | |
2022-02-01 | |
Source Publication | JOURNAL OF COLLOID AND INTERFACE SCIENCE
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ISSN | 0021-9797 |
Volume | 607Pages:655-661 |
Abstract | Owing to the low cost, high energy density, and high theoretical specific capacity, lithium-sulfur batteries have been deemed as a potential choice for future energy storage devices. However, they also have suf-fered from several scientific and technical issues including low conductivity, polysulfides migration, and volume changes. In this study, CoS2-TiO2@carbon core-shell fibers were fabricated through combination of coaxial electrospinning and selective vulcanization method. The core-shell fibers are able to efficiently host sulfur, confine polysulfides, and accelerate intermediates conversion. This electrode delivers an ini-tial specific capacity of 1181.1 mAh g(-1) and a high capacity of 736.5 mAh g(-1) after 300 cycles with high coulombic efficiency over 99.5% (capacity decay of 0.06% per cycle). This strategy of isolating interactant and selective vulcanization provides new ideas for effectively constructing heterostructure materials for lithium-sulfur batteries. (c) 2021 Elsevier Inc. All rights reserved. |
Keyword | Lithium-sulfur batteries Coaxial electrospinning Core-shell fibers Energy |
DOI | 10.1016/j.jcis.2021.08.171 |
Language | 英语 |
WOS Keyword | POLYSULFIDE CONVERSION ; NANOCRYSTALS ; REDOX ; INTERLAYER ; PROGRESS ; STORAGE |
Funding Project | National Natural Science Foundation of China (NSFC)[21975007] ; National Natural Science Foundation of China (NSFC)[21774005] ; National Natural Science Foundation of China (NSFC)[21433012] ; National Natural Science Foundation of China (NSFC)[51772010] ; National Natural Science Foundation for Out-standing Youth Foundation ; Fundamental Research Funds for the Central Universities ; National Program for Support of Top-notch Young Professionals ; 111 project[B14009] |
WOS Research Area | Chemistry |
WOS Subject | Chemistry, Physical |
Funding Organization | National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation for Out-standing Youth Foundation ; Fundamental Research Funds for the Central Universities ; National Program for Support of Top-notch Young Professionals ; 111 project |
WOS ID | WOS:000704395200008 |
Publisher | ACADEMIC PRESS INC ELSEVIER SCIENCE |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/50298 |
Collection | 中国科学院过程工程研究所 |
Corresponding Author | Wang, Nu; Wang, Bao; Zhao, Yong |
Affiliation | 1.Beihang Univ, Key Lab Bioinspired Smart Interfacial Sci & Techn, Minist Educ, Sch Chem, Beijing 100191, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China 3.Inner Mongolia Univ Technol, Chem Engn Coll, Hohhot 010051, Peoples R China |
Recommended Citation GB/T 7714 | Li, Dianming,Li, Hongtai,Zheng, Shumin,et al. CoS2-TiO2@C Core-Shell fibers as cathode host material for High-Performance Lithium-Sulfur batteries[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2022,607:655-661. |
APA | Li, Dianming.,Li, Hongtai.,Zheng, Shumin.,Gao, Ning.,Li, Shuai.,...&Zhao, Yong.(2022).CoS2-TiO2@C Core-Shell fibers as cathode host material for High-Performance Lithium-Sulfur batteries.JOURNAL OF COLLOID AND INTERFACE SCIENCE,607,655-661. |
MLA | Li, Dianming,et al."CoS2-TiO2@C Core-Shell fibers as cathode host material for High-Performance Lithium-Sulfur batteries".JOURNAL OF COLLOID AND INTERFACE SCIENCE 607(2022):655-661. |
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