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| Solvent Effects on Photocatalytic Anaerobic Oxidation of Benzyl Alcohol over Pt-Loaded Defective SrTiO3 Nanoparticles | |
| Hu, Yezi1,2; Shen, Zewen1; Li, Bingfeng1; Li, Shaojun1; Yue, Junrong3; Zhao, Guixia1,2; Muhler, Martin4; Wang, Xiangke1 | |
| 2021-09-24 | |
| Source Publication | ACS APPLIED NANO MATERIALS
 |
| ISSN | 2574-0970 |
| Volume | 4Issue:9Pages:9254-9264 |
| Abstract | Photocatalytic selective oxidation of alcohols under mild conditions is an emerging technique to encounter the global challenges of energy source shortages and the green synthesis perspective. Herein, we investigate the solvent effects on heterogeneous photocatalytic anaerobic oxidation of benzyl alcohol with Pt-loaded defective SrTiO3 nanoparticles. It is found that the optimal solvent is water mixed with a small amount of dimethylformamide (DMF) or acetonitrile, while the solvent effects on the oxidation of benzyl alcohol are related to the adsorption of benzyl alcohol and benzaldehyde on the photocatalysts in different solvents, in which the adsorption of benzyl alcohol plays a major role, while such positive effect can be significantly offset in case the adsorption of benzaldehyde is leading the effort. This work offers the avenue to improve the photocatalytic oxidation of alcohols by optimizing the reaction solvents in addition to the well-known structure engineering of the photocatalysts. |
| Keyword | solvent effects adsorption selective oxidation photocatalysis SrTiO3 nanoparticles |
| DOI | 10.1021/acsanm.1c01750 |
| Language | 英语 |
| WOS Keyword | SELECTIVE OXIDATION ; DOPED SRTIO3 ; AROMATIC ALCOHOLS ; CARBON NITRIDE ; DRIVEN ; DEHYDROGENATION ; HYDROGEN ; WATER ; ADSORPTION ; ALDEHYDES |
| Funding Project | National Natural Science Foundation of China[21976054] ; Fundamental Research Funds for the Central Universities[2020MS036] ; National Key Research and Development Program of China[2017YFA0207002] ; Deutsche Forschungsgemeinschaft (DFG)[SFB/TRR 247] ; Beijing Outstanding Young Scientist Program |
| WOS Research Area | Science & Technology - Other Topics ; Materials Science |
| WOS Subject | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| Funding Organization | National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; National Key Research and Development Program of China ; Deutsche Forschungsgemeinschaft (DFG) ; Beijing Outstanding Young Scientist Program |
| WOS ID | WOS:000702079900061 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/50409 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Zhao, Guixia; Wang, Xiangke |
| Affiliation | 1.North China Elect Power Univ, Coll Environm Sci & Engn, Beijing 102206, Peoples R China 2.Ruhr Univ Bochum, Fac Chem & Biochem, Lab Ind Chem, D-44780 Bochum, Germany 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multi Phase Complex Syst, Beijing 100190, Peoples R China 4.Max Planck Inst Chem Energy Convers, D-45470 Mulheim, Germany |
| Recommended Citation GB/T 7714 | Hu, Yezi,Shen, Zewen,Li, Bingfeng,et al. Solvent Effects on Photocatalytic Anaerobic Oxidation of Benzyl Alcohol over Pt-Loaded Defective SrTiO3 Nanoparticles[J]. ACS APPLIED NANO MATERIALS,2021,4(9):9254-9264. |
| APA | Hu, Yezi.,Shen, Zewen.,Li, Bingfeng.,Li, Shaojun.,Yue, Junrong.,...&Wang, Xiangke.(2021).Solvent Effects on Photocatalytic Anaerobic Oxidation of Benzyl Alcohol over Pt-Loaded Defective SrTiO3 Nanoparticles.ACS APPLIED NANO MATERIALS,4(9),9254-9264. |
| MLA | Hu, Yezi,et al."Solvent Effects on Photocatalytic Anaerobic Oxidation of Benzyl Alcohol over Pt-Loaded Defective SrTiO3 Nanoparticles".ACS APPLIED NANO MATERIALS 4.9(2021):9254-9264. |
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