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Recent progress in one-step synthesis of acrylic acid and methyl acrylate via aldol reaction: Catalyst, mechanism, kinetics and separation
Wang, Gang1,2; Li, Zengxi1,2; Li, Chunshan3,4
2022-01-16
Source PublicationCHEMICAL ENGINEERING SCIENCE
ISSN0009-2509
Volume247Pages:13
AbstractWith the gradual depletion of petroleum resources, the one-step synthesis of acrylic acid/ methyl acrylate from acetic acid/methyl acetate and formaldehyde via aldol reaction, instead of propylene selective oxidation, has stimulated researchers' interest. Current research in this field focus on catalyst modifica-tion, structure-activity relationships, catalytic mechanism and kinetics, and separation process design. The faced challenging problems are efficient catalyst development, mechanism-based kinetics calculation for reactor design and separation process optimization, which hinder the industrial progress, although great efforts have been made in the last decades. Therefore, it is necessary and meaningful to review the achievements as the basis for the further exploration and application in this area. This review aims to systematically summarize and analyze the catalytic performance and structure-activity relationships of developed catalysts, catalytic mechanism and kinetics, and separation process design, as well as sug-gest the prospective research. (c) 2021 Elsevier Ltd. All rights reserved.
KeywordAcrylic acid Methyl acrylate Aldol reaction Mechanism Kinetics Separation
DOI10.1016/j.ces.2021.117052
Language英语
WOS KeywordTITANIUM BINARY PHOSPHATE ; ACETIC-ACID ; CONDENSATION REACTION ; SELECTIVE OXIDATION ; IONIC LIQUID ; ACETATE ; FORMALDEHYDE ; OXIDE ; METHANOL ; PERFORMANCE
Funding ProjectNational Science Found for Distinguished Young Scholars[22025803] ; Key Research Program of Frontier Sciences, CAS[QYZDB-SSW-SLH022] ; National Natural Science Foundation of China[21878293] ; National Natural Science Foundation of China[21676270] ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences[IAGM-2019-A14] ; K. C. Wong Education Foundation[GJTD-2018-04]
WOS Research AreaEngineering
WOS SubjectEngineering, Chemical
Funding OrganizationNational Science Found for Distinguished Young Scholars ; Key Research Program of Frontier Sciences, CAS ; National Natural Science Foundation of China ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences ; K. C. Wong Education Foundation
WOS IDWOS:000705826400013
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/50456
Collection中国科学院过程工程研究所
Corresponding AuthorLi, Zengxi
Affiliation1.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 101408, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
4.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wang, Gang,Li, Zengxi,Li, Chunshan. Recent progress in one-step synthesis of acrylic acid and methyl acrylate via aldol reaction: Catalyst, mechanism, kinetics and separation[J]. CHEMICAL ENGINEERING SCIENCE,2022,247:13.
APA Wang, Gang,Li, Zengxi,&Li, Chunshan.(2022).Recent progress in one-step synthesis of acrylic acid and methyl acrylate via aldol reaction: Catalyst, mechanism, kinetics and separation.CHEMICAL ENGINEERING SCIENCE,247,13.
MLA Wang, Gang,et al."Recent progress in one-step synthesis of acrylic acid and methyl acrylate via aldol reaction: Catalyst, mechanism, kinetics and separation".CHEMICAL ENGINEERING SCIENCE 247(2022):13.
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