Knowledge Management System Of Institute of process engineering,CAS
| Facile in-situ synthesis of floating CeO2@ expanded graphite composites with efficient adsorption and visible light photocatalytic degradation of phenol | |
| Li, Huilin1; Guo, Qiang2; Li, Yongli2; Fu, Mingbo1; Tian, Dengchao1; Qi, Tao2 | |
| 2021-10-01 | |
| Source Publication | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
 |
| Volume | 9Issue:5Pages:13 |
| Abstract | A facile solution to obtain efficient, stable and cheap photocatalysts was conducted in this work. CeO2@ expanded graphite (CeO2/EG) composites were in-situ synthesized with a new strategy, in which CeCl3 molecules inserted the graphite intercalation compound (GIC) and converted into CeO2 as GIC changed into EG via instant calcination. The introduction of EG has accelerated the adsorption of contaminant molecules, promoted the charge transfer and improved the photocatalytic efficiency. The best sample, containing 80.75 wt% CeO2 particles of nanometer scale, has achieved the highest pollutant removal efficiency of 97.3% for phenol, displaying the highest reaction rate constant of 0.0262 min(-1), which was 35.4 times higher than CeO2. Besides, it possesses good stability and keeps floating in water pollution treatment, showing great advantages to work in natural water body. Phenol and its degradation intermediates were identified using HPLC/MS, and appropriate reaction pathways were proposed. |
| Keyword | CeO2 Expanded graphite Adsorption Photocatalysis Phenol |
| DOI | 10.1016/j.jece.2021.106252 |
| Language | 英语 |
| WOS Keyword | SURFACE ; OXIDE ; TIO2 ; HETEROSTRUCTURES ; NANOSTRUCTURES ; PERFORMANCE ; FABRICATION ; GRAPHENE ; CERIA |
| Funding Project | National Key Research and Development Projects of China[2020YFC1909601] ; National Key Research and Development Projects of China[2020YFC1909603] ; Key Deployment Projects of Chinese Academy of Sciences[ZDRWZS201811] ; Key Research and Devel-opment and Promotion Projects of Henan Province[212102310066] |
| WOS Research Area | Engineering |
| WOS Subject | Engineering, Environmental ; Engineering, Chemical |
| Funding Organization | National Key Research and Development Projects of China ; Key Deployment Projects of Chinese Academy of Sciences ; Key Research and Devel-opment and Promotion Projects of Henan Province |
| WOS ID | WOS:000714646000002 |
| Publisher | ELSEVIER SCI LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/50884 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Guo, Qiang; Qi, Tao |
| Affiliation | 1.Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450003, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | Li, Huilin,Guo, Qiang,Li, Yongli,et al. Facile in-situ synthesis of floating CeO2@ expanded graphite composites with efficient adsorption and visible light photocatalytic degradation of phenol[J]. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,2021,9(5):13. |
| APA | Li, Huilin,Guo, Qiang,Li, Yongli,Fu, Mingbo,Tian, Dengchao,&Qi, Tao.(2021).Facile in-situ synthesis of floating CeO2@ expanded graphite composites with efficient adsorption and visible light photocatalytic degradation of phenol.JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,9(5),13. |
| MLA | Li, Huilin,et al."Facile in-situ synthesis of floating CeO2@ expanded graphite composites with efficient adsorption and visible light photocatalytic degradation of phenol".JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 9.5(2021):13. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment