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| The biomimetic engineering of metal-organic frameworks with single-chiral-site precision for asymmetric hydrogenation | |
| Guo, Jun1,2; Duan, Yulong1; Liu, Yangyang3; Li, Huangxu4; Zhang, Yin2; Long, Chang2; Wang, Zuming5; Yang, Yongchao3; Zhao, Shenlong3 | |
| 2021-11-08 | |
| Source Publication | JOURNAL OF MATERIALS CHEMISTRY A
 |
| ISSN | 2050-7488 |
| Pages | 7 |
| Abstract | Asymmetric hydrogenation based on heterogeneous metal nanoparticles (NPs) has attracted extensive attention for the production of chiral chemicals due to its high conversion efficiency, simple product separation, and convenient catalyst regeneration. Nevertheless, its further practical application is still impeded by the leaching of expensive chiral ligands and by the associated extra purification costs that are caused by the weak absorption of the chiral ligands on the metal NPs. In contrast, chiral metal-organic frameworks (CMOFs) have been proposed to serve as metal NP supports and chirality inducers via biomimicry of the configuration of privileged natural cinchona alkaloids on the single-chiral-site level. Among the presented engineered isoreticular valine (Val)-, serine (Ser)-, and threonine (Thr)-derived CMOFs, the Thr-MOF-supported Pt nanoparticles (NPs) exhibit impressive enantioselectivity in the asymmetric hydrogenation of ethyl pyruvate (EP) in addition to inherently robust catalytic recyclability without the need to add either fresh chiral ligands or Pt NPs. |
| DOI | 10.1039/d1ta08319h |
| Language | 英语 |
| WOS Keyword | RECENT PROGRESS ; CATALYSIS ; NANOPARTICLES ; PLATFORM ; SERIES |
| Funding Project | National Natural Science Foundation of China[22103055] ; Science and Technology Plans of Tianjin[21ZYJDJC00050] ; Australian Research Council Discovery Early Career Researcher Award[DE220100676] ; FH Loxton Fellowship of the USYD |
| WOS Research Area | Chemistry ; Energy & Fuels ; Materials Science |
| WOS Subject | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
| Funding Organization | National Natural Science Foundation of China ; Science and Technology Plans of Tianjin ; Australian Research Council Discovery Early Career Researcher Award ; FH Loxton Fellowship of the USYD |
| WOS ID | WOS:000719948000001 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/51075 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Guo, Jun; Zhao, Shenlong |
| Affiliation | 1.Tiangong Univ, Sch Chem, State Key Lab Separat Membranes & Membrane Proc, Tianjin 300387, Peoples R China 2.Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, CAS Key Lab Nanosyst & Hierarch Fabricat, Beijing 100190, Peoples R China 3.Univ Sydney, Sch Chem & Biomol Engn, Sydney, NSW, Australia 4.City Univ Hong Kong, Dept Chem, Hong Kong 999077, Peoples R China 5.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | Guo, Jun,Duan, Yulong,Liu, Yangyang,et al. The biomimetic engineering of metal-organic frameworks with single-chiral-site precision for asymmetric hydrogenation[J]. JOURNAL OF MATERIALS CHEMISTRY A,2021:7. |
| APA | Guo, Jun.,Duan, Yulong.,Liu, Yangyang.,Li, Huangxu.,Zhang, Yin.,...&Zhao, Shenlong.(2021).The biomimetic engineering of metal-organic frameworks with single-chiral-site precision for asymmetric hydrogenation.JOURNAL OF MATERIALS CHEMISTRY A,7. |
| MLA | Guo, Jun,et al."The biomimetic engineering of metal-organic frameworks with single-chiral-site precision for asymmetric hydrogenation".JOURNAL OF MATERIALS CHEMISTRY A (2021):7. |
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