CAS OpenIR
CoNi nano-alloy anchored on biomass-derived N-doped carbon frameworks for enhanced oxygen reduction and evolution reactions
Charles, Victor1,2; Zhang, Xu1,3; Yuan, Menglei1,2; Zhang, Ke4; Cui, Kairui5; Zhang, Jingxian1,2; Zhao, Tongkun1,2; Li, Yaling5; Liu, Zhanjun6; Li, Bin4; Zhang, Guangjin1,2,7
2022-01-10
Source PublicationELECTROCHIMICA ACTA
ISSN0013-4686
Volume402Pages:10
AbstractBifunctional catalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are important for energy conversion systems such as fuel cells, water splitting, and metal-air battery devices. In this work, an earthly abundant and cheap biomass of tobacco-stem was used to prepare a novel porous carbon framework (NiCo@N-C) by incorporating transition metal alloy and nitrogen-rich small molecules. The resultant catalyst affords an onset potential of 0.92 V and a half-wave potential of 0.86 V for oxygen reduction reaction in alkaline media, which is better than commercial Pt/C. Besides, the catalyst also exhibits good oxygen evolution reaction performance with a low overpotential of 280 mV @ 10 mA cm(-2), and the potential gap between ORR and OER is only 0.65 V. The incorporation of NiCo alloy and N heteroatom modulates the electronic structure of the prepared carbon frameworks, creates abundant active sites, and improves charge redistribution, thus resulting in faster ORR and OER reaction kinetics. The applicability of the prepared NiCo@N-C is fully harnessed for use as an air-cathode in a Zn-air battery. This work creates a platform for developing efficient porous and functionalized biomass-derived oxygen electrocatalysts for energy applications. (C) 2021 Elsevier Ltd. All rights reserved.
KeywordBiomass Bifunctional electrocatalysts Zn-air batteries Porous carbon Oxygen evolution Overpotential
DOI10.1016/j.electacta.2021.139555
Language英语
WOS KeywordBIFUNCTIONAL ELECTROCATALYSTS ; POROUS CARBON ; EFFICIENT ELECTROCATALYSTS ; AIR BATTERIES ; NITROGEN ; COBALT ; NANOFIBERS ; NANOTUBES ; CATALYSTS ; GRAPHENE
Funding ProjectNational Natural Science Foundation of China[21776021] ; National Key R&D Program of China[2020YFA0710201] ; Key Program for International S&T Cooperation Projects - Ministry of Science and Technology of China[2018YFE0124600] ; Cross-Training Plan for High-Level Talents in Beijing Colleges and Universities[EC202005] ; Chemistry and Chemical Engineering Guangdong Laboratory[1922006]
WOS Research AreaElectrochemistry
WOS SubjectElectrochemistry
Funding OrganizationNational Natural Science Foundation of China ; National Key R&D Program of China ; Key Program for International S&T Cooperation Projects - Ministry of Science and Technology of China ; Cross-Training Plan for High-Level Talents in Beijing Colleges and Universities ; Chemistry and Chemical Engineering Guangdong Laboratory
WOS IDWOS:000722049200011
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/51096
Collection中国科学院过程工程研究所
Corresponding AuthorLi, Bin; Zhang, Guangjin
Affiliation1.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
3.Shenyang Univ Chem Engn, Shenyang 110142, Peoples R China
4.Zhengzhou Tobacco Res Inst CNTC, Zhengzhou 450001, Henan, Peoples R China
5.Beijing Inst Graph Commun, Beijing Engn Res Ctr Printed Elect, Beijing 102627, Peoples R China
6.Chinese Acad Sci, Inst Coal Chem, CAS Key Lab Carbon Mat, Taiyuan 030001, Peoples R China
7.Chem & Chem Engn Guangdong Lab, Shantou 515031, Peoples R China
Recommended Citation
GB/T 7714
Charles, Victor,Zhang, Xu,Yuan, Menglei,et al. CoNi nano-alloy anchored on biomass-derived N-doped carbon frameworks for enhanced oxygen reduction and evolution reactions[J]. ELECTROCHIMICA ACTA,2022,402:10.
APA Charles, Victor.,Zhang, Xu.,Yuan, Menglei.,Zhang, Ke.,Cui, Kairui.,...&Zhang, Guangjin.(2022).CoNi nano-alloy anchored on biomass-derived N-doped carbon frameworks for enhanced oxygen reduction and evolution reactions.ELECTROCHIMICA ACTA,402,10.
MLA Charles, Victor,et al."CoNi nano-alloy anchored on biomass-derived N-doped carbon frameworks for enhanced oxygen reduction and evolution reactions".ELECTROCHIMICA ACTA 402(2022):10.
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