CAS OpenIR
Electronic and lattice strain dual tailoring for boosting Pd electrocatalysis in oxygen reduction reaction
Zeng, Qing1,2; Liu, Danye1,2; Liu, Hui1,3; Cui, Penglei1; Hu, Chaoquan1,3; Chen, Dong1,3; Xu, Lin4; Wu, Xiang5; Yang, Jun1,2,3
2021-11-19
Source PublicationISCIENCE
Volume24Issue:11Pages:16
AbstractDeliberately optimizing the d-band position of an active component via electronic and lattice strain tuning is an effective way to boost its catalytic performance. We herein demonstrate this concept by constructing core-shell Au@NiPd nanoparticles with NiPd alloy shells of only three atomic layers through combining an Au catalysis with the galvanic replacement reaction. The Au core with larger electronegativity modulates the Pd electronic configuration, while the Ni atoms alloyed in the ultrrathin shells neutralize the lattice stretching in Pd shells exerted by Au cores, equipping the active Pd metal with a favorable d-band position for electrochemical oxygen reduction reaction in an alkaline medium, for which core-shell Au@NiPd nanoparticles with a Ni/Pd atomic ratio of 3/7 exhibit a half-wave potential of 0.92 V, specific activity of 3.7 mA cm(2), and mass activity of 0.65 A mg(-1) at 0.9 V, much better than most of the recently reported Pd-even Pt-based electrocatalysts.
DOI10.1016/j.isci.2021.103332
Language英语
WOS KeywordTOTAL-ENERGY CALCULATIONS ; FORMIC-ACID OXIDATION ; CATALYTIC-ACTIVITY ; CARBON ; NANOPARTICLES ; ORR ; PERFORMANCE ; DURABILITY ; NANOCUBES ; GRAPHENE
Funding ProjectNational Natural Science Foundation of China[22075290] ; National Natural Science Foundation of China[21972068] ; National Natural Science Foundation of China[21776292] ; National Natural Science Foundation of China[21706265] ; Beijing Natural Science Foundation[Z200012] ; State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences[MPCS-2021-A-05] ; Nanjing IPE Institute of Green Manufacturing Industry
WOS Research AreaScience & Technology - Other Topics
WOS SubjectMultidisciplinary Sciences
Funding OrganizationNational Natural Science Foundation of China ; Beijing Natural Science Foundation ; State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences ; Nanjing IPE Institute of Green Manufacturing Industry
WOS IDWOS:000730163700002
PublisherCELL PRESS
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Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/51434
Collection中国科学院过程工程研究所
Corresponding AuthorChen, Dong; Xu, Lin; Yang, Jun
Affiliation1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, 19A Yuquan Rd, Beijing 100049, Peoples R China
3.Nanjing IPE Inst Green Mfg Ind, Nanjing 211100, Jiangsu, Peoples R China
4.Nanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China
5.Shenyang Univ Technol, Sch Mat Sci & Engn, Shenyang 110870, Peoples R China
Recommended Citation
GB/T 7714
Zeng, Qing,Liu, Danye,Liu, Hui,et al. Electronic and lattice strain dual tailoring for boosting Pd electrocatalysis in oxygen reduction reaction[J]. ISCIENCE,2021,24(11):16.
APA Zeng, Qing.,Liu, Danye.,Liu, Hui.,Cui, Penglei.,Hu, Chaoquan.,...&Yang, Jun.(2021).Electronic and lattice strain dual tailoring for boosting Pd electrocatalysis in oxygen reduction reaction.ISCIENCE,24(11),16.
MLA Zeng, Qing,et al."Electronic and lattice strain dual tailoring for boosting Pd electrocatalysis in oxygen reduction reaction".ISCIENCE 24.11(2021):16.
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