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A nanoscale qualitative study on the role of sodium hydrosulfide in oxidized carrollite flotation
Zhao, Haiping1,2,3; Ruan, Renman1,2; Niu, Xiaopeng1,2; Li, Li1,2; Zhang, Enpu4
2021-11-01
Source PublicationINTERNATIONAL JOURNAL OF MINING SCIENCE AND TECHNOLOGY
ISSN2095-2686
Volume31Issue:6Pages:1085-1093
AbstractThe surface species transformation of oxidized carrollite processing with NaHS and KBX was investigated. Flotation and contact angle tests indicate that the combination of NaHS and KBX takes a better flotation performance than adding NaHS or KBX alone. Thermodynamic analysis, X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) results confirm the stronger chemisorption of KBX occurs on the oxidized carrollite surface with NaHS, which is beneficial to remove the cobalt oxides, thus contributing to the superior floatability. Interestingly, less elemental sulfur was observed on the carrollite surface as the interaction of NaHS and KBX than adding NaHS alone. It suggests that elemental sulfur is not the main contributor to the restored floatability of oxidized carrollite through sulfidisation. This study provided a new perspective to correlate the surface species with xanthate adsorption and oxidized carrollite flotation through determining the various intermediate products. (C) 2021 Published by Elsevier B.V. on behalf of China University of Mining & Technology.
KeywordOxidized carrollite Sulfidisation Sodium hydrosulfide Potassium butyl xanthate Interaction Chemisorption
DOI10.1016/j.ijmst.2021.10.008
Language英语
WOS KeywordCOLLECTORLESS FLOTATION ; SURFACE-PROPERTIES ; COPPER RECOVERY ; PYRITE ; SULFIDE ; CHALCOPYRITE ; OXIDATION ; XANTHATE ; COBALT ; ADSORPTION
Funding ProjectInnovation Academy for Green Manufacture, Chinese Academy of Sciences[IAGM-2019A08]
WOS Research AreaMining & Mineral Processing
WOS SubjectMining & Mineral Processing
Funding OrganizationInnovation Academy for Green Manufacture, Chinese Academy of Sciences
WOS IDWOS:000736792900011
PublisherELSEVIER
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/51569
Collection中国科学院过程工程研究所
Corresponding AuthorRuan, Renman
Affiliation1.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Wanbao Min LTD, Beijing 100053, Peoples R China
Recommended Citation
GB/T 7714
Zhao, Haiping,Ruan, Renman,Niu, Xiaopeng,et al. A nanoscale qualitative study on the role of sodium hydrosulfide in oxidized carrollite flotation[J]. INTERNATIONAL JOURNAL OF MINING SCIENCE AND TECHNOLOGY,2021,31(6):1085-1093.
APA Zhao, Haiping,Ruan, Renman,Niu, Xiaopeng,Li, Li,&Zhang, Enpu.(2021).A nanoscale qualitative study on the role of sodium hydrosulfide in oxidized carrollite flotation.INTERNATIONAL JOURNAL OF MINING SCIENCE AND TECHNOLOGY,31(6),1085-1093.
MLA Zhao, Haiping,et al."A nanoscale qualitative study on the role of sodium hydrosulfide in oxidized carrollite flotation".INTERNATIONAL JOURNAL OF MINING SCIENCE AND TECHNOLOGY 31.6(2021):1085-1093.
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