CAS OpenIR
A New Process for Peracetic Acid Production from Acetic Acid and Hydrogen Peroxide Based on Kinetic Modeling and Distillation Simulation
Liu, Shuaifeng1,2; Zhang, Xiaojuan1,3; Asselin, Edouard3; Li, Zhibao1
2021-12-28
Source PublicationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
Pages10
AbstractThe reaction kinetics of peracetic acid from acetic acid and hydrogen peroxide in a helical capillary microreactor was investigated and modeled via regression of the measured conversion rate of hydrogen peroxide. It was found that the activity of the proton in the sulfuric acid solution played a significant role in the synthesis as a catalyst. The activities of the proton were calculated with the ELECNRTL equation and used to obtain a kinetic model with apparent activation energies of peracetic acid synthesis and hydrolysis of 53.63 and 54.45 kJ/mol, respectively. A new continuous process for industrial manufacture of peracetic acid solution (30 wt %) was proposed, where the reacted solution from the microreactor is distilled to separate unreacted reactants and sulfuric acid, which are recycled as a feed. The feasibility of the new process was validated by Aspen Plus simulation and economic assessment.
DOI10.1021/acs.iecr.1c04211
Language英语
WOS KeywordWASTE-WATER ; FLOW
Funding ProjectNational Science Foundation of China[21506218] ; National Science Foundation of China[21476235] ; National Science Foundation of China[U1407112]
WOS Research AreaEngineering
WOS SubjectEngineering, Chemical
Funding OrganizationNational Science Foundation of China
WOS IDWOS:000737866900001
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/51594
Collection中国科学院过程工程研究所
Corresponding AuthorAsselin, Edouard; Li, Zhibao
Affiliation1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China
3.Univ British Columbia, Dept Mat Engn, Vancouver, BC V6T 1Z4, Canada
Recommended Citation
GB/T 7714
Liu, Shuaifeng,Zhang, Xiaojuan,Asselin, Edouard,et al. A New Process for Peracetic Acid Production from Acetic Acid and Hydrogen Peroxide Based on Kinetic Modeling and Distillation Simulation[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2021:10.
APA Liu, Shuaifeng,Zhang, Xiaojuan,Asselin, Edouard,&Li, Zhibao.(2021).A New Process for Peracetic Acid Production from Acetic Acid and Hydrogen Peroxide Based on Kinetic Modeling and Distillation Simulation.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,10.
MLA Liu, Shuaifeng,et al."A New Process for Peracetic Acid Production from Acetic Acid and Hydrogen Peroxide Based on Kinetic Modeling and Distillation Simulation".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2021):10.
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