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Efficient Extraction of Manganese from Low-Grade Pyrolusite by a Sawdust Pyrolysis Reduction Roasting-Acid Leaching Process
Ju, Jinrong1,2,3; Feng, Yali1; Li, Haoran2,3; Zhong, Xiaofeng1
2022-02-28
Source PublicationJOM
ISSN1047-4838
Pages11
AbstractIn this work, a novel method for extraction of manganese from low-grade pyrolusite by a sawdust pyrolysis reduction roasting-acid leaching process was explored. The reduction roasting was studied systematically, and the mechanism was also explored by thermodynamic and phase change analysis. Results indicate that sawdust was rapidly pyrolyzed at 250-450 degrees C to generate a large amount of reducing gases such as CO, CH4, and H-2, which gradually reduced MnO2 in low-grade pyrolusite to MnO. The reduction process of MnO2 was identified as MnO2 -> Mn2O3 -> Mn3O4 -> MnO. It was proved that MnO2 of low-grade pyrolusite could be reduced effectively to MnO at lower temperature and shorter duration time by sawdust pyrolysis. Meanwhile, the optimum leaching efficiency of 99.45% for manganese could be attained when sawdust dosage was 11% of the mass of low-grade pyrolusite, the roasting temperature was 500 degrees C, and the roasting time was 25 min.
DOI10.1007/s11837-022-05215-1
Language英语
WOS KeywordTHERMOCHEMICAL CHARACTERISTICS ; DIELECTRIC-PROPERTIES ; REDUCING AGENTS ; BIOMASS ; ORE ; KINETICS ; MIXTURES ; OPTIMIZATION ; WASTES ; PYRITE
Funding ProjectChina Ocean Mineral Resources RD Association[JS-KTHT-2019-01]
WOS Research AreaMaterials Science ; Metallurgy & Metallurgical Engineering ; Mineralogy ; Mining & Mineral Processing
WOS SubjectMaterials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering ; Mineralogy ; Mining & Mineral Processing
Funding OrganizationChina Ocean Mineral Resources RD Association
WOS IDWOS:000762149900005
PublisherSPRINGER
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Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/52161
Collection中国科学院过程工程研究所
Corresponding AuthorJu, Jinrong
Affiliation1.Univ Sci & Technol Beijing, Civil & Resource Engn Sch, Beijing 100083, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Key Lab Biochem Engn, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Ju, Jinrong,Feng, Yali,Li, Haoran,et al. Efficient Extraction of Manganese from Low-Grade Pyrolusite by a Sawdust Pyrolysis Reduction Roasting-Acid Leaching Process[J]. JOM,2022:11.
APA Ju, Jinrong,Feng, Yali,Li, Haoran,&Zhong, Xiaofeng.(2022).Efficient Extraction of Manganese from Low-Grade Pyrolusite by a Sawdust Pyrolysis Reduction Roasting-Acid Leaching Process.JOM,11.
MLA Ju, Jinrong,et al."Efficient Extraction of Manganese from Low-Grade Pyrolusite by a Sawdust Pyrolysis Reduction Roasting-Acid Leaching Process".JOM (2022):11.
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