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Preparation and characterization of a solar-driven sodium acetate trihydrate composite phase change material with Ti4O7 particles
Wang, Hui1,2; Zhang, Ying2; Ci, Enda2; Li, Xiaoqing1; Guo, Lijiang2; Wu, Liu2; Li, Jianqiang1
2022-05-01
Source PublicationSOLAR ENERGY MATERIALS AND SOLAR CELLS
ISSN0927-0248
Volume238Pages:9
AbstractThermal energy storage using phase change materials has received much attention as it can effectively relieve the contradiction of renewable energy between supply and demand. The novel bifunctional sodium acetate trihydrate (SAT) composite phase change materials with photo-thermal conversion and heat storage properties were developed to promote the thermal utilization of solar energy. The Ti4O7 particles were selected as photo-thermal conversion media with full spectral absorption of sunlight and efficient photo-thermal conversion performance. 5 wt% disodium hydrogen phosphate dodecahydrate (DSP) and 3 wt% carboxymethyl cellulose were used to decrease supercooling and restrain phase separation of SAT, respectively. The as-prepared SAT composites with different content of Ti4O7 possess a low supercooling degree of 0.9-1.5 degrees C and high latent heat of 228.6-257.7 kJ kg(-1). Ti4O7 has a stable absorption capacity covering the full solar spectrum (200-2500 nm) and the absorption capacity of SAT and DSP in the infrared light even more than Ti4O7 at 1900 nm-2500 nm. The SAT composite sample with 10 wt% Ti4O7 has the best total solar absorption capacity of 93.33% more than Ti4O7 of 92.76% because SAT and DSP have outstanding absorption capacity in the long-wave infrared wavelength. The photo thermal storage efficiency of all SAT composite photo-thermal conversion phase change materials exceeds 50%, of which the composite with 10 wt% Ti4O7 has the optimal photo-thermal conversion storage efficiency of 76.63%. The composite photo-thermal storage phase change materials have potential applications in solar energy systems.
KeywordPhase change materials Photo-thermal conversion Sodium acetate trihydrate Ti O-4(7) particles
DOI10.1016/j.solmat.2022.111591
Language英语
WOS KeywordTHERMAL-ENERGY STORAGE ; HIGH-TEMPERATURE ; COMBUSTION PROCESSES ; MIXTURE FORMATION ; ROTARY ENGINE ; CONVERSION ; PERFORMANCE ; CONDUCTIVITY ; NANOFLUIDS ; STABILITY
Funding ProjectFund of State Key Laboratory of Multiphase Complex Systems[MPCS-2021-A-01] ; National Natural Science Foundation of China[51971208] ; Fundamental Research Funds for the Central Universities
WOS Research AreaEnergy & Fuels ; Materials Science ; Physics
WOS SubjectEnergy & Fuels ; Materials Science, Multidisciplinary ; Physics, Applied
Funding OrganizationFund of State Key Laboratory of Multiphase Complex Systems ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities
WOS IDWOS:000763946300004
PublisherELSEVIER
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Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/52261
Collection中国科学院过程工程研究所
Corresponding AuthorLi, Jianqiang
Affiliation1.Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
2.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wang, Hui,Zhang, Ying,Ci, Enda,et al. Preparation and characterization of a solar-driven sodium acetate trihydrate composite phase change material with Ti4O7 particles[J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS,2022,238:9.
APA Wang, Hui.,Zhang, Ying.,Ci, Enda.,Li, Xiaoqing.,Guo, Lijiang.,...&Li, Jianqiang.(2022).Preparation and characterization of a solar-driven sodium acetate trihydrate composite phase change material with Ti4O7 particles.SOLAR ENERGY MATERIALS AND SOLAR CELLS,238,9.
MLA Wang, Hui,et al."Preparation and characterization of a solar-driven sodium acetate trihydrate composite phase change material with Ti4O7 particles".SOLAR ENERGY MATERIALS AND SOLAR CELLS 238(2022):9.
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