CAS OpenIR
Transferring Liquid Metal to form a Hybrid Solid Electrolyte via a Wettability-Tuning Technology for Lithium-Metal Anodes
Jin, Xin1,2,3; Cai, Ziqiang1,2; Zhang, Xinrui3,4; Yu, Jianming1,2; He, Qiya3,5; Lu, Zhenda1,2; Dahbi, Mouad6; Alami, Jones6; Lu, Jun7; Amine, Khalil7,8; Zhang, Huigang1,2,3,5
2022-03-20
Source PublicationADVANCED MATERIALS
ISSN0935-9648
Pages11
AbstractIntegrating solid-state electrolyte (SSE) into Li-metal anodes has demonstrated great promise to unleash the high energy density of rechargeable Li-metal batteries. However, fabricating a highly cyclable SSE/Li-metal anode remains a major challenge because the densification of the SSE is usually incompatible with the reactive Li metal. Here, a liquid-metal-derived hybrid solid electrolyte (HSE) is proposed, and a facile transfer technology to construct an artificial HSE on the Li metal is reported. By tuning the wettability of the transfer substrates, electron- and ion-conductive liquid metal is sandwiched between electron-insulating and ion-conductive LiF and oxides to form the HSE. The transfer technology renders the HSE continuous, dense, and uniform. The HSE, having high ion transport, electron shut-off, and mechanical strength, makes the composite anode deliver excellent cyclability for over 4000 h at 0.5 mA cm(-2) and 1 mAh cm(-2) in a symmetrical cell. When pairing with LiFePO4 and sulfur cathodes, the HSE-coated Li metal dramatically enhances the performance of full cells. Therefore, this work demonstrates that tuning the interfacial wetting properties provides an alternate approach to build a robust solid electrolyte, which enables highly efficient Li-metal anodes.
KeywordLi-metal anodes liquid metals solid electrolyte transfer technology wettability
DOI10.1002/adma.202200181
Language英语
WOS KeywordHIGH-ENERGY ; INTERPHASE ; BATTERY ; CONDUCTIVITY ; NUCLEATION ; DEPOSITION ; NITROGEN ; GROWTH
Funding ProjectNational Key Research and Development Program of China[2020YFA0406104] ; National Natural Science Foundation of China[22075131] ; State Key Laboratory of Multiphase Complex Systems[MPCS-2021-A] ; Clean Vehicles, US-China Clean Energy Research Centre (CERC-CVC2) under US DOE EERE Vehicle Technologies Office ; DOE[DE-AC02-06CH11357]
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
Funding OrganizationNational Key Research and Development Program of China ; National Natural Science Foundation of China ; State Key Laboratory of Multiphase Complex Systems ; Clean Vehicles, US-China Clean Energy Research Centre (CERC-CVC2) under US DOE EERE Vehicle Technologies Office ; DOE
WOS IDWOS:000770840400001
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/52438
Collection中国科学院过程工程研究所
Corresponding AuthorLu, Jun; Amine, Khalil; Zhang, Huigang
Affiliation1.Nanjing Univ, Natl Lab Solid State Microstruct, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Jiangsu, Peoples R China
2.Nanjing Univ, Coll Engn & Appl Sci, Nanjing 210093, Jiangsu, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
4.Shaanxi Normal Univ, Sch Chem & Chem Engn, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Shaanxi, Peoples R China
5.Northwest Univ, Sch Chem Engn, Shaanxi R&D Ctr Biomat & Fermentat Engn, Shaanxi Key Lab Degradable Biomed Mat, Taibai North Rd 229, Xian 710069, Shaanxi, Peoples R China
6.Mohammed VI Polytech Univ, Mat Sci & Nanoengn Dept, Ben Guerir, Morocco
7.Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA
8.Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA
Recommended Citation
GB/T 7714
Jin, Xin,Cai, Ziqiang,Zhang, Xinrui,et al. Transferring Liquid Metal to form a Hybrid Solid Electrolyte via a Wettability-Tuning Technology for Lithium-Metal Anodes[J]. ADVANCED MATERIALS,2022:11.
APA Jin, Xin.,Cai, Ziqiang.,Zhang, Xinrui.,Yu, Jianming.,He, Qiya.,...&Zhang, Huigang.(2022).Transferring Liquid Metal to form a Hybrid Solid Electrolyte via a Wettability-Tuning Technology for Lithium-Metal Anodes.ADVANCED MATERIALS,11.
MLA Jin, Xin,et al."Transferring Liquid Metal to form a Hybrid Solid Electrolyte via a Wettability-Tuning Technology for Lithium-Metal Anodes".ADVANCED MATERIALS (2022):11.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Jin, Xin]'s Articles
[Cai, Ziqiang]'s Articles
[Zhang, Xinrui]'s Articles
Baidu academic
Similar articles in Baidu academic
[Jin, Xin]'s Articles
[Cai, Ziqiang]'s Articles
[Zhang, Xinrui]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Jin, Xin]'s Articles
[Cai, Ziqiang]'s Articles
[Zhang, Xinrui]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.