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Coating conductive polypyrrole layers on multiple shells of hierarchical SnO2 spheres and their enhanced cycling stability as lithium-ion battery anode | |
Li, Bo1,2; Bi, Ruyi1; Yang, Mei1; Gao, Wei2; Wang, Jiangyan1,3 | |
2022-06-01 | |
Source Publication | APPLIED SURFACE SCIENCE
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ISSN | 0169-4332 |
Volume | 586Pages:7 |
Abstract | SnO2 has been considered as an attractive anode material for lithium-ion batteries. However, its poor cycling life due to dramatic volume change during cycling processes hinders its commercial application. Herein, a facile approach has been proposed to coat conductive polypyrrole layers on every shell of hierarchical SnO2 spheres with a hollow multishelled structure (SnO2@Ppy HoMS). The Ppy layers as a framework on every SnO2 shell can both improve the conductivity and maintain the structural integrity during charging-discharging processes. The composite with multishelled SnO2 as active material can enhance the energy density of the battery, and the voids between shells accommodate the volume expansion. Thanks to these merits, the SnO2@Ppy HoMS anode delivers excellent electrochemical performance, achieving impressive cycling stability of 782 mAh g(-1) after 650 cycles at a current density of 0.25?degrees C and an ultra-rapid and stable charge-discharge performance of 580 mAh g(-1) at 4C for 5000th cycles. |
Keyword | SnO(2 & nbsp In-situ polymerization Long cycle life Lithium-ion battery Polypyrrole coating )anode |
DOI | 10.1016/j.apsusc.2022.152836 |
Language | 英语 |
WOS Keyword | HOLLOW SPHERES ; PERFORMANCE ; NANOCOMPOSITE ; MICROSPHERES ; NANOCRYSTALS ; NANOWIRE ; ARRAYS |
Funding Project | National Natural Sci-ence Foundation of China[51972305] |
WOS Research Area | Chemistry ; Materials Science ; Physics |
WOS Subject | Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter |
Funding Organization | National Natural Sci-ence Foundation of China |
WOS ID | WOS:000776118800005 |
Publisher | ELSEVIER |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/52481 |
Collection | 中国科学院过程工程研究所 |
Corresponding Author | Wang, Jiangyan |
Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, 1 North 2nd St, Beijing 100190, Peoples R China 2.Univ Auckland, Dept Chem & Mat Engn, Fac Engn, Pb Auckland 92019, New Zealand 3.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 10049, Peoples R China |
First Author Affilication | Center of lonic Liquids and Green Engineering |
Corresponding Author Affilication | Center of lonic Liquids and Green Engineering |
Recommended Citation GB/T 7714 |
Li, Bo,Bi, Ruyi,Yang, Mei,et al. Coating conductive polypyrrole layers on multiple shells of hierarchical SnO2 spheres and their enhanced cycling stability as lithium-ion battery anode [J]. APPLIED SURFACE SCIENCE,2022,586:7. |
APA |
Li, Bo,Bi, Ruyi,Yang, Mei,Gao, Wei,&Wang, Jiangyan.(2022). Coating conductive polypyrrole layers on multiple shells of hierarchical SnO2 spheres and their enhanced cycling stability as lithium-ion battery anode .APPLIED SURFACE SCIENCE,586,7. |
MLA |
Li, Bo,et al." Coating conductive polypyrrole layers on multiple shells of hierarchical SnO2 spheres and their enhanced cycling stability as lithium-ion battery anode ".APPLIED SURFACE SCIENCE 586(2022):7. |
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