CAS OpenIR
Constructing stable lithium interfaces via coordination of fluorinated ether and liquid crystal for room-temperature solid-state lithium metal batteries
Li, Jin1,2,3; Huo, Feng1,2,3; Yang, Yaxi1,4; Chen, Tianhua1,5; Cui, Yingyue1,2,3; Cai, Yingjun1,3; Zhang, Haitao1,2,3
2022-04-01
Source PublicationCHEMICAL ENGINEERING JOURNAL
ISSN1385-8947
Volume433Pages:9
AbstractThe poor compatibility of the electrodes/solid-state electrolytes (SSEs) interfaces of rechargeable room-temperature solid-state lithium metal batteries (RTSSLMBs) limit their rapid development and commercializa-tion. Herein, fluorinated ether as a block and liquid crystal 4,4 "& nbsp;-Azoxyanisole as an additive are firstly used to fabricate robust SSEs for RTSSLMBs. A combination of in-situ polymerization and the construction of stable interfaces is employed to obtain excellent cycling performance in LMBs. We propose the mechanism of regulating the lithium anode interfaces by 4,4 "-Azoxyanisole with high anchoring strength in SSEs. Liquid crystal with high anchoring strength ensures the smooth electrodeposition of lithium metal, and fluorinated ether provides rich LiF for SEI, which is beneficial to inhibit the growth of lithium dendrite. The electrochemical test shows that symmetrical lithium batteries maintain steadily operation over 3500 h. Further, the novel 3D fiber-network SPEs exhibit high ionic conductivity of 0.13 mS/cm at room temperature, a wide electrochemical stability window of 4.9 V, a high lithium-ion transference number of 0.42, and better mechanical strength (Young's modulus of 6.3 GPa). As a consequence, superior cycling stability is demonstraced in Li/LiFePO4 batteries at ambient temper-ature. In addition, the reaction mechanism is verified by density functional theory calculations and various electrochemical characterizations. This new and universal strategy may be a new route to suppress Li dendrites, it will be helpful for the commercialization and application of RTSSLMBs.
KeywordSolid-state electrolytes Interface Fluorinated ether Free radical Liquid crystal
DOI10.1016/j.cej.2021.133562
Language英语
WOS KeywordHIGH IONIC-CONDUCTIVITY ; POLYMER ELECTROLYTE ; ELECTRODEPOSITION ; STRATEGIES ; PROTECTION ; TRANSPORT ; CHANNELS ; NETWORK ; DESIGN ; ANODE
Funding ProjectNational Key Research and Development Program of China[2019YFA0705601] ; National Natural Science Foundation of China[21878308] ; Major Program of National Natural Science Foundation of China[21890762] ; K.C.Wong Education Foundation[GJTD-2018-04] ; Science and Technology Service Network Initiative program of CAS[KFJ-STS-QYZD-2021-02-002]
WOS Research AreaEngineering
WOS SubjectEngineering, Environmental ; Engineering, Chemical
Funding OrganizationNational Key Research and Development Program of China ; National Natural Science Foundation of China ; Major Program of National Natural Science Foundation of China ; K.C.Wong Education Foundation ; Science and Technology Service Network Initiative program of CAS
WOS IDWOS:000774551100004
PublisherELSEVIER SCIENCE SA
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/52510
Collection中国科学院过程工程研究所
Corresponding AuthorCai, Yingjun; Zhang, Haitao
Affiliation1.Chinese Acad Sci, Beijing Key Lab Ionic Liquids Clean Proc, Inst Proc Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
4.Zhengzhou Univ, Sch Chem Engn, Zhengzhou 450000, Peoples R China
5.Univ Adelaide, Sch Chem Engn & Adv Mat, Adelaide, SA 5005, Australia
Recommended Citation
GB/T 7714
Li, Jin,Huo, Feng,Yang, Yaxi,et al. Constructing stable lithium interfaces via coordination of fluorinated ether and liquid crystal for room-temperature solid-state lithium metal batteries[J]. CHEMICAL ENGINEERING JOURNAL,2022,433:9.
APA Li, Jin.,Huo, Feng.,Yang, Yaxi.,Chen, Tianhua.,Cui, Yingyue.,...&Zhang, Haitao.(2022).Constructing stable lithium interfaces via coordination of fluorinated ether and liquid crystal for room-temperature solid-state lithium metal batteries.CHEMICAL ENGINEERING JOURNAL,433,9.
MLA Li, Jin,et al."Constructing stable lithium interfaces via coordination of fluorinated ether and liquid crystal for room-temperature solid-state lithium metal batteries".CHEMICAL ENGINEERING JOURNAL 433(2022):9.
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