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Synthesis of Tunable-Acidity Vanadium Phosphorus Oxide CatalystsModified by Layered Double Oxide for the Selective Oxidation ofn-Butane br
Zhang, Huiling1,2; Dong, Jie1,2; Li, Yingwei1,2; Chen, Fan1,2; Zhang, Ruirui1,2; Xiang, Xu3,4; Liu, Ruixia1,2; He, Jing3,4; Zhang, Suojiang1,2
2022-03-23
Source PublicationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
Volume61Issue:11Pages:3850-3859
AbstractA series of tunable-acidity vanadium phosphorus oxide (VPO) catalysts modified by layered double oxide (LDO)werefirst fabricated by a mechanical milling approach. The optimum Zn2Mg1Al1O-VPO sample achieved 63.2% yield of maleicanhydride (MA), which is 8.9% higher than that of Blank-VPO. Various characterizations were used to explore the relationshipbetween the surface properties such as the crystal structure, surface P/V ratio, surface acidity, and catalytic performance. The NH3-TPD and pyridine IR analysis demonstrated that the appropriate surface acidity could significantly improve the performance of theVPO catalyst. A synergistic catalysis mechanism between the Lewis and Bronsted acid sites is tentatively proposed to enhance thecatalytic performance of VPO. The Lewis acid sites accelerate the C-H bond activation and cleavage, thereby increasing theconversion ofn-butane. Moreover, the Bronsted acid sites can stabilize the reaction intermediates and facilitate the desorption ofMA, consequently improving the selectivity of MA.
DOI10.1021/acs.iecr.1c03760
Language英语
WOS KeywordN-BUTANE ; VPO CATALYSTS ; BENZOIC-ACID ; ACETIC-ACID ; PHOSPHATE ; HYDROGENATION ; PHASE ; DEHYDROGENATION ; CHEMISTRY ; (VO)2P2O7
Funding ProjectNational Key Research and Development Program of China[2017YFA0206803] ; National Nature Science Foundation of China[22078338] ; Major Program of National Science Foundation of China[21890760] ; Key Programs of the Chinese Academy of Sciences[KFZD-SW-413] ; K.C. Wong Education Foundation[GJTD-2018-04]
WOS Research AreaEngineering
WOS SubjectEngineering, Chemical
Funding OrganizationNational Key Research and Development Program of China ; National Nature Science Foundation of China ; Major Program of National Science Foundation of China ; Key Programs of the Chinese Academy of Sciences ; K.C. Wong Education Foundation
WOS IDWOS:000776193100005
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/52570
Collection中国科学院过程工程研究所
Corresponding AuthorLiu, Ruixia; He, Jing; Zhang, Suojiang
Affiliation1.Inst Proc Engn, State Key Lab Multiphase Complex Syst, CAS Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China
3.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
4.Beijing Univ Chem Technol, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, Beijing 100029, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Huiling,Dong, Jie,Li, Yingwei,et al. Synthesis of Tunable-Acidity Vanadium Phosphorus Oxide CatalystsModified by Layered Double Oxide for the Selective Oxidation ofn-Butane br[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2022,61(11):3850-3859.
APA Zhang, Huiling.,Dong, Jie.,Li, Yingwei.,Chen, Fan.,Zhang, Ruirui.,...&Zhang, Suojiang.(2022).Synthesis of Tunable-Acidity Vanadium Phosphorus Oxide CatalystsModified by Layered Double Oxide for the Selective Oxidation ofn-Butane br.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,61(11),3850-3859.
MLA Zhang, Huiling,et al."Synthesis of Tunable-Acidity Vanadium Phosphorus Oxide CatalystsModified by Layered Double Oxide for the Selective Oxidation ofn-Butane br".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 61.11(2022):3850-3859.
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