| Aerobic Oxidation of Benzyl Alcohol over Activated Carbon Supported Manganese and Vanadium Catalysts: Effect of Surface Oxygen-Containing Groups | |
| Chen, Yuanting1; Chen, Wan1; Tang, Qinghu1; Guo, Zhen1; Yang, Yanhui1; Su, Fabing2; Yang, YH | |
| 2011 | |
| Source Publication | CATALYSIS LETTERS
 |
| ISSN | 1011-372X |
| Volume | 141Issue:1Pages:149-157 |
| Abstract | In this contribution, the selective oxidation of benzyl alcohol using molecular oxygen over supported manganese and vanadium catalysts was investigated. The catalytic activities were significantly improved after pre-oxidizing the activated carbon support materials. Characterizations of nitrogen physisorption, X-ray diffraction, transmission electron microscopy, and X-ray absorption were involved to examine the physicochemical properties of as-prepared catalysts. By ruling out the effects of specific surface area, active site dispersion, valence and local coordination of Mn and V active species, the improved catalytic activity was attributed to the specific variety and increased density of oxygen-containing groups on activated carbon support surfaces, which was further confirmed by cyclic voltammetry measurements and Fourier transform infrared spectroscopy. |
| Keyword | Activated Carbon Surface Oxygen Manganese Oxides Vanadium Oxides Benzyl Alcohol Oxidation |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1007/s10562-010-0447-4 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Keyword | ABSORPTION FINE-STRUCTURE ; SELECTIVE OXIDATION ; RUTHENIUM CATALYSTS ; AROMATIC ALCOHOLS ; PLATINUM ; CINNAMALDEHYDE ; HYDROGENATION ; CHEMISTRY ; PERFORMANCE ; EPOXIDATION |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Physical |
| WOS ID | WOS:000286380900019 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Version | 出版稿 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/5258 |
| Collection | 多相复杂系统国家重点实验室 |
| Corresponding Author | Yang, YH |
| Affiliation | 1.Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore 2.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | Chen, Yuanting,Chen, Wan,Tang, Qinghu,et al. Aerobic Oxidation of Benzyl Alcohol over Activated Carbon Supported Manganese and Vanadium Catalysts: Effect of Surface Oxygen-Containing Groups[J]. CATALYSIS LETTERS,2011,141(1):149-157. |
| APA | Chen, Yuanting.,Chen, Wan.,Tang, Qinghu.,Guo, Zhen.,Yang, Yanhui.,...&Yang, YH.(2011).Aerobic Oxidation of Benzyl Alcohol over Activated Carbon Supported Manganese and Vanadium Catalysts: Effect of Surface Oxygen-Containing Groups.CATALYSIS LETTERS,141(1),149-157. |
| MLA | Chen, Yuanting,et al."Aerobic Oxidation of Benzyl Alcohol over Activated Carbon Supported Manganese and Vanadium Catalysts: Effect of Surface Oxygen-Containing Groups".CATALYSIS LETTERS 141.1(2011):149-157. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 20131108-1026-复件 s10（812KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | Application Full Text | |
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