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| Polymetallic Molybdenum-Based Catalysts for Epimerization of Glucose to Mannose | |
Peng, Fubin1,2,3; Sun, Ying3; Hua, Chao4,5,6; Bai, Fang4,5,6 ; Ma, Hong3; Hu, Xiangping3; Liu, Xin3,7; Zhang, Meiyun3,7; Wang, Xinhong1,2
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| 2022-04-05 | |
| Source Publication | CHEMISTRYSELECT
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| ISSN | 2365-6549 |
| Volume | 7Issue:13Pages:8 |
| Abstract | Molybdenum-based catalysts have been widely studied in the epimerization of glucose to mannose. In this paper, several polymetallic molybdenum-based catalysts were prepared and the high activity and selectivity of catalysts containing different divalent metal ions were investigated. Unlike most previous studies, there is no need to add acid to adjust pH in this reaction. It was found that the yield of CuAlMoO4 and CuAgAlMoO4 catalysts could be kept above 28.9 % at the epimerization of glucose reaction. Compared with soluble Cu3Mo2O9 catalysts, the prepared catalysts showed better stability and catalytic activity during the reaction process. It was found that the catalysts without copper had no catalytic effect or poor catalytic effect, and the valence state of copper ion changed before and after the reaction, indicating that copper ion played a very important role in the reaction. |
| Keyword | CuAlMoO4 CuAgAlMoO4 epimerization glucose mannose |
| DOI | 10.1002/slct.202103224 |
| Language | 英语 |
| WOS Keyword | MOLYBDATE IONS ; PHOTOLUMINESCENCE PROPERTIES ; SELECTIVE DEHYDRATION ; D-FRUCTOSE ; ISOMERIZATION ; EFFICIENT ; ACID ; ALDOSES ; SITES ; CU |
| Funding Project | Innovation Academy for Green Manufacture, Chinese Academy of Sciences[IAGM2020C08] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDA21030400] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDB17020300] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| Funding Organization | Innovation Academy for Green Manufacture, Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences |
| WOS ID | WOS:000777721700001 |
| Publisher | WILEY-V C H VERLAG GMBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/52619 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Sun, Ying; Hua, Chao; Wang, Xinhong |
| Affiliation | 1.Dalian Polytech Univ, Sch Text, Dalian 116034, Peoples R China 2.Dalian Polytech Univ, Mat Engn Inst, Dalian 116034, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 4.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China 5.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 6.Univ Chinese Acad Sci, Sch Chem & Engn, Beijing 100049, Peoples R China 7.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Corresponding Author Affilication | Center of lonic Liquids and Green Engineering |
| Recommended Citation GB/T 7714 | Peng, Fubin,Sun, Ying,Hua, Chao,et al. Polymetallic Molybdenum-Based Catalysts for Epimerization of Glucose to Mannose[J]. CHEMISTRYSELECT,2022,7(13):8. |
| APA | Peng, Fubin.,Sun, Ying.,Hua, Chao.,Bai, Fang.,Ma, Hong.,...&Wang, Xinhong.(2022).Polymetallic Molybdenum-Based Catalysts for Epimerization of Glucose to Mannose.CHEMISTRYSELECT,7(13),8. |
| MLA | Peng, Fubin,et al."Polymetallic Molybdenum-Based Catalysts for Epimerization of Glucose to Mannose".CHEMISTRYSELECT 7.13(2022):8. |
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