CAS OpenIR
Polymetallic Molybdenum-Based Catalysts for Epimerization of Glucose to Mannose
Peng, Fubin1,2,3; Sun, Ying3; Hua, Chao4,5,6; Bai, Fang4,5,6; Ma, Hong3; Hu, Xiangping3; Liu, Xin3,7; Zhang, Meiyun3,7; Wang, Xinhong1,2
2022-04-05
Source PublicationCHEMISTRYSELECT
ISSN2365-6549
Volume7Issue:13Pages:8
AbstractMolybdenum-based catalysts have been widely studied in the epimerization of glucose to mannose. In this paper, several polymetallic molybdenum-based catalysts were prepared and the high activity and selectivity of catalysts containing different divalent metal ions were investigated. Unlike most previous studies, there is no need to add acid to adjust pH in this reaction. It was found that the yield of CuAlMoO4 and CuAgAlMoO4 catalysts could be kept above 28.9 % at the epimerization of glucose reaction. Compared with soluble Cu3Mo2O9 catalysts, the prepared catalysts showed better stability and catalytic activity during the reaction process. It was found that the catalysts without copper had no catalytic effect or poor catalytic effect, and the valence state of copper ion changed before and after the reaction, indicating that copper ion played a very important role in the reaction.
KeywordCuAlMoO4 CuAgAlMoO4 epimerization glucose mannose
DOI10.1002/slct.202103224
Language英语
WOS KeywordMOLYBDATE IONS ; PHOTOLUMINESCENCE PROPERTIES ; SELECTIVE DEHYDRATION ; D-FRUCTOSE ; ISOMERIZATION ; EFFICIENT ; ACID ; ALDOSES ; SITES ; CU
Funding ProjectInnovation Academy for Green Manufacture, Chinese Academy of Sciences[IAGM2020C08] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDA21030400] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDB17020300]
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
Funding OrganizationInnovation Academy for Green Manufacture, Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences
WOS IDWOS:000777721700001
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/52619
Collection中国科学院过程工程研究所
Corresponding AuthorSun, Ying; Hua, Chao; Wang, Xinhong
Affiliation1.Dalian Polytech Univ, Sch Text, Dalian 116034, Peoples R China
2.Dalian Polytech Univ, Mat Engn Inst, Dalian 116034, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
4.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China
5.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
6.Univ Chinese Acad Sci, Sch Chem & Engn, Beijing 100049, Peoples R China
7.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Peng, Fubin,Sun, Ying,Hua, Chao,et al. Polymetallic Molybdenum-Based Catalysts for Epimerization of Glucose to Mannose[J]. CHEMISTRYSELECT,2022,7(13):8.
APA Peng, Fubin.,Sun, Ying.,Hua, Chao.,Bai, Fang.,Ma, Hong.,...&Wang, Xinhong.(2022).Polymetallic Molybdenum-Based Catalysts for Epimerization of Glucose to Mannose.CHEMISTRYSELECT,7(13),8.
MLA Peng, Fubin,et al."Polymetallic Molybdenum-Based Catalysts for Epimerization of Glucose to Mannose".CHEMISTRYSELECT 7.13(2022):8.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Peng, Fubin]'s Articles
[Sun, Ying]'s Articles
[Hua, Chao]'s Articles
Baidu academic
Similar articles in Baidu academic
[Peng, Fubin]'s Articles
[Sun, Ying]'s Articles
[Hua, Chao]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Peng, Fubin]'s Articles
[Sun, Ying]'s Articles
[Hua, Chao]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.