Catalytic effect of Ag+ and Cu2+ on leaching realgar (As2S2) | |
Guo, Pei1,2; Zhang, Guangji1,2; Cao, Junya3; Li, Yuanyuan3; Fang, Zhaoheng1,2; Yang, Chao1,2; Zhang, GJ | |
2011-02-01 | |
Source Publication | HYDROMETALLURGY
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ISSN | 0304-386X |
Volume | 106Issue:1-2Pages:99-103 |
Abstract | The catalytic effect of Ag+ and Cu2+ on the dissolution of realgar was studied. In the absence of these catalysis ions, little realgar can be leached by Fe3+ either with or without bacteria. Silver ion can enhance the chemical leaching and bioleaching rate remarkably, while the catalytic effect of copper(II) ion was not so obvious. The catalytic mechanism of Ag+ and Cu2+ was similar: the surface arsenic was replaced by the formation of Ag2S or CuS, which was then dissolved by Fe3+. With Ag+ added, the influences of concentration of Fe3+ and temperature on chemical leaching were also investigated. (C) 2010 Elsevier B.V. All rights reserved. |
Keyword | Realgar Bioleaching Ferric Leaching Silver Catalysis Copper Catalysis |
Subtype | Article |
WOS Headings | Science & Technology ; Technology |
DOI | 10.1016/j.hydromet.2010.12.006 |
Indexed By | SCI |
Language | 英语 |
WOS Keyword | MIXED CULTURES ; CHALCOPYRITE ; SULFIDE ; PART ; OXIDATION ; PROGRESS ; IONS ; GOLD ; ACID |
WOS Research Area | Metallurgy & Metallurgical Engineering |
WOS Subject | Metallurgy & Metallurgical Engineering |
WOS ID | WOS:000287952600016 |
Citation statistics | |
Document Type | 期刊论文 |
Version | 出版稿 |
Identifier | http://ir.ipe.ac.cn/handle/122111/5264 |
Collection | 生化工程国家重点实验室 |
Corresponding Author | Zhang, GJ |
Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 3.China Univ Min & Technol, Sch Chem & Environm Engn, Beijing 100083, Peoples R China |
Recommended Citation GB/T 7714 | Guo, Pei,Zhang, Guangji,Cao, Junya,et al. Catalytic effect of Ag+ and Cu2+ on leaching realgar (As2S2)[J]. HYDROMETALLURGY,2011,106(1-2):99-103. |
APA | Guo, Pei.,Zhang, Guangji.,Cao, Junya.,Li, Yuanyuan.,Fang, Zhaoheng.,...&Zhang, GJ.(2011).Catalytic effect of Ag+ and Cu2+ on leaching realgar (As2S2).HYDROMETALLURGY,106(1-2),99-103. |
MLA | Guo, Pei,et al."Catalytic effect of Ag+ and Cu2+ on leaching realgar (As2S2)".HYDROMETALLURGY 106.1-2(2011):99-103. |
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