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A strategy of synergistically using ether oxygen and phenolic hydroxyl groups for Ultra-High selective and fast Cs+ isolation
Xu, Zihao1,2; Rong, Meng1,2; Ni, Shan1,2; Meng, Qiyu1,2; Chen, Liyan1,2; Liu, Huizhou1,2; Yang, Liangrong1,2
2022-02-01
Source PublicationSEPARATION AND PURIFICATION TECHNOLOGY
ISSN1383-5866
Volume284Pages:11
AbstractHypercrosslinked polymers (HCPs) with synergistic effect of ether oxygen and phenolic hydroxyl groups was designed and fabricated for Cs+ isolation in the salt lake system. The separation factors (S.F.)(Cs+/K+) of the adsorbents were significantly increased through regulating the content of the ether oxygen group in the frameworks. The S.F. of PO-HCPs-6 was increased by nearly 5 times to an ultra-high value (S.F. = 57) compared with the Cs+ adsorbents reported in the literature. Moreover, the mild and sufficient polymerization process endowed PO-HCPs-6 with an extremely fast kinetic adsorption rate. PO-HCPs-6 could quickly reach 90% of the equilibrium adsorption capacity in just 1 min. Finally, after 5 times adsorption-desorption experiments, the remarkable elution rate (> 92%) and reusability adsorption capacity (> 91%) of PO-HCPs-6 proved it has inspiring application potential for the Cs+ isolation in the salt lake brine system.
KeywordSynergistic effect Phenolic hydroxyl and ether oxygen groups High selectivity Cesium isolation Salt lake brine
DOI10.1016/j.seppur.2021.120285
Language英语
WOS KeywordION-EXCHANGE ; AMMONIUM MOLYBDOPHOSPHATE ; SOLVENT-EXTRACTION ; MICROPOROUS POLYMERS ; AQUEOUS-SOLUTIONS ; CESIUM ; REMOVAL ; ADSORPTION ; WASTE ; ADSORBENT
Funding ProjectNational Key R&D Program of China[2021YFC2901500] ; National Natural Science Foundation of China[21922814] ; National Natural Science Foundation of China[22138012] ; National Natural Science Foundation of China[21961160745] ; National Natural Science Foundation of China[21921005] ; National Natural Science Foundation of China[22178349] ; National Natural Science Foundation of China[22078333] ; National Natural Science Foundation of China[22108281] ; National Natural Science Foundation of China[31961133019] ; Excellent Member in Youth Innovation Promotion Association, Chinese Academy of Sciences[Y202014] ; Shandong Energy Insititute[SEI I202133] ; China Postdoctoral Science Foundation[2021 M703239] ; Key Research Program of the Chinese Academy of Sciences[ZDRW-CN-2021-3]
WOS Research AreaEngineering
WOS SubjectEngineering, Chemical
Funding OrganizationNational Key R&D Program of China ; National Natural Science Foundation of China ; Excellent Member in Youth Innovation Promotion Association, Chinese Academy of Sciences ; Shandong Energy Insititute ; China Postdoctoral Science Foundation ; Key Research Program of the Chinese Academy of Sciences
WOS IDWOS:000780757100001
PublisherELSEVIER
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/52685
Collection中国科学院过程工程研究所
Corresponding AuthorYang, Liangrong
Affiliation1.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Xu, Zihao,Rong, Meng,Ni, Shan,et al. A strategy of synergistically using ether oxygen and phenolic hydroxyl groups for Ultra-High selective and fast Cs+ isolation[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2022,284:11.
APA Xu, Zihao.,Rong, Meng.,Ni, Shan.,Meng, Qiyu.,Chen, Liyan.,...&Yang, Liangrong.(2022).A strategy of synergistically using ether oxygen and phenolic hydroxyl groups for Ultra-High selective and fast Cs+ isolation.SEPARATION AND PURIFICATION TECHNOLOGY,284,11.
MLA Xu, Zihao,et al."A strategy of synergistically using ether oxygen and phenolic hydroxyl groups for Ultra-High selective and fast Cs+ isolation".SEPARATION AND PURIFICATION TECHNOLOGY 284(2022):11.
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