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| Chemoenzymatic Cascade Reaction for Green Cleaning of Polyamide Nanofiltration Membrane | |
| Zhang, Jinxuan1,2; Zhang, Huiru1,2; Wan, Yinhua1,3; Luo, Jianquan1,2 | |
| 2022-03-16 | |
| Source Publication | ACS APPLIED MATERIALS & INTERFACES
 |
| ISSN | 1944-8244 |
| Volume | 14Issue:10Pages:12204-12213 |
| Abstract | Chemical cleaning is indispensable for the sustainable operation of nanofiltration (NF) in wastewater treatment. However, the common chemical cleaning methods are plagued by low cleaning efficiency, high chemical consumption, and separation performance deterioration. In this work, a chemoenzymatic cascade reaction is proposed for pollutant degradation and polyamide NF membrane cleaning. Glucose oxidase (GOD) enzymatic reaction in this cascade system produces hydrogen peroxide (H2O2) and gluconic acid to trigger the oxidation of foulants by Fe3O4 catalyzed Fenton reaction. By virtue of the microenvironment (pH and H2O2 concentration) engineering and substrate enrichments, this chemoenzymatic cascade reaction (GOD-Fe3O4) exhibits a favorable degradation efficiency for bisphenol A and methyl blue (MB). Thanks to the strong oxidizing degradation, the water flux of the NF10 membrane fouled by MB is almost completely recovered (similar to 95.8%) after a 3-cycle fouling/cleaning experiment. Meanwhile, the chemoenzymatic cascade reaction improves the applicability of the Fenton reaction in polyamide NF membrane cleaning because it prevents the membrane from damaging by high concentration of H2O2 and inhibits the secondary fouling caused by ferric hydroxide precipitates. By immobilizing GOD on the aminated Fe3O4 nanoparticles, a reusable cleaning agent is prepared for highly efficient membrane cleaning. This chemoenzymatic cascade reaction without the addition of an acid/base/oxidant provides a promising candidate for sustainable and cost-effective cleaning for the polyamide NF membrane. |
| Keyword | hydrogen peroxide Fenton reaction chemoenzymatic cascade reaction membrane fouling membrane cleaning |
| DOI | 10.1021/acsami.1c23466 |
| Language | 英语 |
| WOS Keyword | WASTE-WATER ; OSMOSIS MEMBRANES ; FENTON REACTION ; DEGRADATION ; OXIDATION ; RECOVERY |
| Funding Project | National Natural Science Foundation of China[21878306] ; Beijing Natural Science Foundation[2192053] |
| WOS Research Area | Science & Technology - Other Topics ; Materials Science |
| WOS Subject | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| Funding Organization | National Natural Science Foundation of China ; Beijing Natural Science Foundation |
| WOS ID | WOS:000787549000017 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/53054 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Luo, Jianquan |
| Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Ganjiang Innovat Acad, Ganzhou 341000, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang, Jinxuan,Zhang, Huiru,Wan, Yinhua,et al. Chemoenzymatic Cascade Reaction for Green Cleaning of Polyamide Nanofiltration Membrane[J]. ACS APPLIED MATERIALS & INTERFACES,2022,14(10):12204-12213. |
| APA | Zhang, Jinxuan,Zhang, Huiru,Wan, Yinhua,&Luo, Jianquan.(2022).Chemoenzymatic Cascade Reaction for Green Cleaning of Polyamide Nanofiltration Membrane.ACS APPLIED MATERIALS & INTERFACES,14(10),12204-12213. |
| MLA | Zhang, Jinxuan,et al."Chemoenzymatic Cascade Reaction for Green Cleaning of Polyamide Nanofiltration Membrane".ACS APPLIED MATERIALS & INTERFACES 14.10(2022):12204-12213. |
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