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| Insight on the effect of Ni and Ni-N co-doping on SnO2 anode materials for lithium-ion batteries | |
| Shi, Jianjian1; Chen, Tao1; Song, Minhang2; Sun, Xiaoli3,4 | |
| 2022-05-05 | |
| Source Publication | RSC ADVANCES
 |
| Volume | 12Issue:22Pages:13971-13974 |
| Abstract | With the increased demand for high-rate performance Li-ion batteries, it is necessary to find available methods to improve the rate properties of SnO2 electrodes. It is noteworthy that doping was considered to be a feasible means. The electronic structures and diffusion energy barriers of Ni-doped and Ni-N co-doped SnO2 were calculated based on density functional theory. The results estimated that the energy gaps of Ni-doped and Ni-N co-doped SnO2 are 1.07 eV and 0.94 eV, which both are smaller than the value of 2.08 eV of SnO2. These exhibit that the conduction properties of SnO2 can be enhanced by doping with the Ni or Ni-N atoms. Moreover, the diffusion properties of Li can also be improved by doping with Ni-N atoms due to the diffusion energy barrier of Li from the B to C point for Ni-N co-doped SnO2 being 0.12 eV smaller than the value of 0.24 eV for the pristine SnO2. Meanwhile, the diffusion energy barriers of Li along other pathways for Ni-N co-doped SnO2 are almost the same as 0.24 eV for SnO2. These results show that both the electronic and ionic conductivity of SnO2 can be enhanced by Ni-N co-doping, which provides a theoretical explanation to promote the rate properties of SnO2 by Ni-N co-doping as anode materials for Li-ion batteries. |
| DOI | 10.1039/d2ra01145j |
| Language | 英语 |
| WOS Keyword | TIN DIOXIDE ; 1ST-PRINCIPLES ; LI ; SURFACE ; OXYGEN |
| Funding Project | Fund Project of Chengdu Technological University[2020RC004] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| Funding Organization | Fund Project of Chengdu Technological University |
| WOS ID | WOS:000792805700001 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/53337 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Chen, Tao; Sun, Xiaoli |
| Affiliation | 1.Chengdu Technol Univ, Sch Elect Engn, Chengdu 611730, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China 3.Tsinghua Univ, Dept Energy & Power Engn, Beijing 100084, Peoples R China 4.Beijing Graphene Inst, Beijing 100095, Peoples R China |
| Recommended Citation GB/T 7714 | Shi, Jianjian,Chen, Tao,Song, Minhang,et al. Insight on the effect of Ni and Ni-N co-doping on SnO2 anode materials for lithium-ion batteries[J]. RSC ADVANCES,2022,12(22):13971-13974. |
| APA | Shi, Jianjian,Chen, Tao,Song, Minhang,&Sun, Xiaoli.(2022).Insight on the effect of Ni and Ni-N co-doping on SnO2 anode materials for lithium-ion batteries.RSC ADVANCES,12(22),13971-13974. |
| MLA | Shi, Jianjian,et al."Insight on the effect of Ni and Ni-N co-doping on SnO2 anode materials for lithium-ion batteries".RSC ADVANCES 12.22(2022):13971-13974. |
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