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Thin-film composite nanofiltration membrane with unprecedented stability in strong acid for highly selective dye/NaCl separation

Ji, Miaozhou1; Wang, Zhenggong1; Zhu, Yuzhang2; Shan, Linglong3; Lu, Yang2; Zhang, Yuping2; Zhang, Yatao4; Jin, Jian1
2022-03-05
Source PublicationJOURNAL OF MEMBRANE SCIENCE
ISSN0376-7388
Volume645Pages:8
AbstractDesigning and preparing nanofiltration (NF) membrane with distinguished property of acidic tolerance is attractive for handling acidic saline wastewater. In this work, we used a new monomer of 2,2-bis(3-amino-4-hydroxyphenyl)-hexafluoro-propane (bisAPAF) to prepare NF membrane by interfacial polymerization for removing dyes from acidic saline solution. Interestingly, the resulted NF membrane derived from bisAPAF and 1,3,5-trimesyol chloride (TMC) exhibits an exceptional structure stability under strong acid condition. Specifically, after exposed to H2SO4 aqueous solution with concentration of 20% (w/v) for 720 h, the NF maintains a Na2SO4 rejection of ~87%, showing little change as compared with the membrane without acidic treatment. In addition, the membrane shows a high selectivity for differentiating Direct Red 23/NaCl or Congo Red/NaCl in the pH range of 2-9, the rejection of dyes maintains at higher than 98% while the NaCl rejection is lower that ~10%. The outstanding acid tolerance property of NF membrane makes it a great promise candidate for acid wastewater remediation.
KeywordNanofiltration membrane Acid resistance

Dye/NaCl separation

Interfacial polymerization
DOI10.1016/j.memsci.2021.120189
Language英语
WOS KeywordNF MEMBRANES ; NAPHTHALENE-1,3,6-TRISULFONYLCHLORIDE NTSC ; INTERFACIAL POLYMERIZATION ; REMOVAL ; PERFORMANCE ; WATER ; FABRICATION ; POLYAMIDE ; CHLORIDE ; REUSE
Funding ProjectNational Natural Science Foundation of China[21988102] ; National Natural Science Foundation of China[51873230] ; National Natural Science Foundation of China[51625306] ; National Key Research and Development Plan[2019YFA0705800] ; Youth Innovation Promotion Association CAS ; CAS-TWAS Centre of Excellence for Green Technology
WOS Research AreaEngineering ; Polymer Science
WOS SubjectEngineering, Chemical ; Polymer Science
Funding OrganizationNational Natural Science Foundation of China ; National Key Research and Development Plan ; Youth Innovation Promotion Association CAS ; CAS-TWAS Centre of Excellence for Green Technology
WOS IDWOS:000791996400006
PublisherELSEVIER
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/53345
Collection中国科学院过程工程研究所
Corresponding AuthorZhu, Yuzhang; Jin, Jian
Affiliation1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
2.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, I Lab, Suzhou 215123, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
4.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Peoples R China
Recommended Citation
GB/T 7714
Ji, Miaozhou,Wang, Zhenggong,Zhu, Yuzhang,et al.

Thin-film composite nanofiltration membrane with unprecedented stability in strong acid for highly selective dye/NaCl separation

[J]. JOURNAL OF MEMBRANE SCIENCE,2022,645:8.
APA Ji, Miaozhou.,Wang, Zhenggong.,Zhu, Yuzhang.,Shan, Linglong.,Lu, Yang.,...&Jin, Jian.(2022).

Thin-film composite nanofiltration membrane with unprecedented stability in strong acid for highly selective dye/NaCl separation

.JOURNAL OF MEMBRANE SCIENCE,645,8.
MLA Ji, Miaozhou,et al."

Thin-film composite nanofiltration membrane with unprecedented stability in strong acid for highly selective dye/NaCl separation

".JOURNAL OF MEMBRANE SCIENCE 645(2022):8.
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