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| Measurement and Correlation of Solubility of Methyl 1,2,4-Triazole-3-carboxylate in 14 Pure Solvents from 278.15 to 318.15 K br | |
| Li, Yang1; Liu, Kejia1; Meng, Long1,2; Wang, Yong1,2 | |
| 2022-05-12 | |
| Source Publication | JOURNAL OF CHEMICAL AND ENGINEERING DATA
 |
| ISSN | 0021-9568 |
| Volume | 67Issue:5Pages:1259-1266 |
| Abstract | The solubility of methyl 1,2,4-triazole-3-carboxylatein 14 solvents (methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, isobutyl alcohol, acetonitrile, acetone, 2-pentanone, 3-pentanone, 4-methyl-2-pentanone, cyclopentanone, cyclohexa-none, tetrahydrofuran) in the range from 278.15 to 318.15 Kand at atmospheric pressure was measured in this study. Thesolubility of methyl 1,2,4-triazole-3-carboxylate in all solventsincreases with the increasing temperature. The solubility of methyl1,2,4-triazole-3-carboxylate in the solvents except for methanol andcyclohexanone does not show much difference, and is significantlysmaller than that in methanol and cyclohexanone. The solubility ofmethyl 1,2,4-triazole-3-carboxylate is not strictly related to polarityof the solvents as it is to the existence of other factors. The solubility of methyl 1,2,4-triazole-3-carboxylate was correlated by the lambda hequation, modified Apelblat model, and Yaws model. The Yaws model is the best one among the three models with average relativedeviation (ARD) and average root-mean-square deviation (104(RMSD)) of 1.18% and 0.364. The work in this study providesimportant solubility data for purification and synthesis of methyl 1,2,4-triazole-3-carboxylate. |
| DOI | 10.1021/acs.jced.1c00957 |
| Language | 英语 |
| WOS Keyword | THERMODYNAMIC PROPERTIES ; WATER ; MONOSOLVENTS ; MIXTURES |
| Funding Project | Self-deployed Projects of Ganjiang Innovation Academy, Chinese Academy of Sciences[E055A002] ; Jiangxi Province Key Laboratory of Cleaner Production of Rare Earths[E03MYB03] ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences[IAGM 2020DA02] ; Key Research Program of the Chinese Academy of Sciences[ZDRW-CN-2021-3-3] |
| WOS Research Area | Thermodynamics ; Chemistry ; Engineering |
| WOS Subject | Thermodynamics ; Chemistry, Multidisciplinary ; Engineering, Chemical |
| Funding Organization | Self-deployed Projects of Ganjiang Innovation Academy, Chinese Academy of Sciences ; Jiangxi Province Key Laboratory of Cleaner Production of Rare Earths ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences |
| WOS ID | WOS:000803148500021 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/53536 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Wang, Yong |
| Affiliation | 1.Chinese Acad Sci, Ganjiang Innovat Acad, Ganzhou 341000, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | Li, Yang,Liu, Kejia,Meng, Long,et al. Measurement and Correlation of Solubility of Methyl 1,2,4-Triazole-3-carboxylate in 14 Pure Solvents from 278.15 to 318.15 K br[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2022,67(5):1259-1266. |
| APA | Li, Yang,Liu, Kejia,Meng, Long,&Wang, Yong.(2022).Measurement and Correlation of Solubility of Methyl 1,2,4-Triazole-3-carboxylate in 14 Pure Solvents from 278.15 to 318.15 K br.JOURNAL OF CHEMICAL AND ENGINEERING DATA,67(5),1259-1266. |
| MLA | Li, Yang,et al."Measurement and Correlation of Solubility of Methyl 1,2,4-Triazole-3-carboxylate in 14 Pure Solvents from 278.15 to 318.15 K br".JOURNAL OF CHEMICAL AND ENGINEERING DATA 67.5(2022):1259-1266. |
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