CAS OpenIR
Vanadium phosphorus oxide catalyst: Progress, development and applications
Faizan, Muhammad1,2; Zhang, Ruirui1; Liu, Ruixia1,2,3
2022-06-25
Source PublicationJOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
ISSN1226-086X
Volume110Pages:27-67
AbstractWith the increasing awareness of carbon neutrality, the global warming issue has been well addressed for the reduction of carbon emissions into the atmosphere. Enormous amounts of carbonaceous gaseous byproducts have already been released into the atmosphere especially after the start of industrial revolution in the last century. Most industrial processes releases low carbon alkanes directly into the environment. Among them petroleum refinery units generate low carbon alkanes especially n-butane as gaseous byproducts. In recent decades, n-butane has been used as a reagent to generate important valuable chemicals such as maleic anhydride with the support of vanadia catalysts. The complex vanadium phosphorus oxide exists in the nature in almost fifteen different phases. Each one has distinguished structural morphology and chemical composition, and exhibits particular physiochemical characteristics such as surface acidity, lattice oxygen, surface oxygen, valance state, P/V ratio, V+4/V+5, surface to lattice oxygen ratio, etc., which are highly dependent on the precursor preparation and catalyst activation conditions. Researchers believed that either the addition of various promoters/cocatalysts/metals-dopants, or introducing new preparation techniques such as microwave irradiation, ultrasound, ball milling, barothermal, calcination, sol-gel method electrospinning, hydrothermal and solvothermal synthesis can be used for the improvement of the catalytic selectivity and activity. Aforementioned different aspects are described in the current review along with the description of reaction kinetics and reaction mechanism. Additionally, we have also highlighted the important industrial issues such as air/n-butane pretreatment, deactivation, water supplement, phosphorus supplement, and the strong exothermic reaction, which are influencing the overall catalytic performance. (c) 2022 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
KeywordCarbon neutrality N-butane selective oxidation Vanadium phosphorus oxide Maleic anhydride Reaction kinetics
DOI10.1016/j.jiec.2022.02.049
Language英语
WOS KeywordN-BUTANE OXIDATION ; GAS-PHASE OXIDATION ; MALEIC-ANHYDRIDE SYNTHESIS ; HIGHLY SELECTIVE CATALYST ; LASER RAMAN-SPECTROSCOPY ; DEEP-EUTECTIC SOLVENTS ; MIXED-METAL OXIDES ; P-O CATALYSTS ; VPO CATALYSTS ; PHOSPHATE CATALYSTS
Funding ProjectNational Key Research and Development Program of China, China[2017YFA0206803] ; Innovation Academy for Green Manufacture of Chinese Academy of Science, China[IAGM2020C17] ; Joint Fund of the Yulin University ; Dalian National Laboratory for Clean Energy, China[2021016] ; K. C. Wong Education Foundation, China[GJTD-2018-04]
WOS Research AreaChemistry ; Engineering
WOS SubjectChemistry, Multidisciplinary ; Engineering, Chemical
Funding OrganizationNational Key Research and Development Program of China, China ; Innovation Academy for Green Manufacture of Chinese Academy of Science, China ; Joint Fund of the Yulin University ; Dalian National Laboratory for Clean Energy, China ; K. C. Wong Education Foundation, China
WOS IDWOS:000802534300003
PublisherELSEVIER SCIENCE INC
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/53543
Collection中国科学院过程工程研究所
Corresponding AuthorLiu, Ruixia
Affiliation1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst,Inst Proc En, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450000, Peoples R China
Recommended Citation
GB/T 7714
Faizan, Muhammad,Zhang, Ruirui,Liu, Ruixia. Vanadium phosphorus oxide catalyst: Progress, development and applications[J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,2022,110:27-67.
APA Faizan, Muhammad,Zhang, Ruirui,&Liu, Ruixia.(2022).Vanadium phosphorus oxide catalyst: Progress, development and applications.JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,110,27-67.
MLA Faizan, Muhammad,et al."Vanadium phosphorus oxide catalyst: Progress, development and applications".JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY 110(2022):27-67.
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