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Heterojunctioned CuO/Cu 2 O catalyst for highly efficient ozone removal
Ma, Guojun1,2,3; Tang, Wenxiang4; Wang, Anqi1,3; Zhang, Le1,3; Guan, Jian1,3; Han, Ning1,2,3; Chen, Yunfa1,2,3
2023-03-01
Source PublicationJOURNAL OF ENVIRONMENTAL SCIENCES
ISSN1001-0742
Volume125Pages:340-348
AbstractIn recent years, near surface ozone pollution, has attracted more and more attention, which necessitates the development of high efficient and low cost catalysts. In this work, CuO/Cu 2 O heterojunctioned catalyst is fabricated by heating Cu 2 O at high temperature, and is adopted as ozone decomposition catalyst. The results show that after Cu 2 O is heated at 180 ??C conversion of ozone increases from 75.2% to 89.3% at mass space velocity 1,920,000 cm 3 /(g ??hr) in dry air with 1000 ppmV ozone, which indicates that this heterojunction catalyst is one of the most efficient catalysts reported at present. Catalysts are characterized by electron paramagnetic resonance spectroscopy and ultraviolet photoelectron spectroscopy, which confirmed that the heterojunction promotes the electron transfer in the catalytic process and creates more defects and oxygen vacancies in the CuO/Cu 2 O interfaces. This procedure of manufacturing heterostructures would also be applicable to other metal oxide catalysts, and it is expected to be more widely applied to the synthesis of high-efficiency heterostructured catalysts in the future. ?? 2022 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.
KeywordCu 2 O Ozone decomposition CuO Heterojunction
DOI10.1016/j.jes.2022.01.0321001-0742
Language英语
WOS KeywordCUPROUS-OXIDE ; CO OXIDATION ; AIR-POLLUTION ; BAND-GAP ; DECOMPOSITION ; CU2O ; TEMPERATURE ; XPS ; NANOSTRUCTURES ; DEGRADATION
Funding ProjectChengdu Science and Technology Program[2019YF05-01833-SN]
WOS Research AreaEnvironmental Sciences & Ecology
WOS SubjectEnvironmental Sciences
Funding OrganizationChengdu Science and Technology Program
WOS IDWOS:000798821400016
PublisherSCIENCE PRESS
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/53620
Collection中国科学院过程工程研究所
Corresponding AuthorHan, Ning; Chen, Yunfa
Affiliation1.Chinese Acad Sci, Inst Proc Engn, Key Lab Sci & Technol Particle Mat, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Ctr Excellence Reg Atmospher Environm, Inst Urban Environm, Xiamen 361021, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
4.Sichuan Univ, Sch Chem Engn, Chengdu 610065, Peoples R China
Recommended Citation
GB/T 7714
Ma, Guojun,Tang, Wenxiang,Wang, Anqi,et al. Heterojunctioned CuO/Cu 2 O catalyst for highly efficient ozone removal[J]. JOURNAL OF ENVIRONMENTAL SCIENCES,2023,125:340-348.
APA Ma, Guojun.,Tang, Wenxiang.,Wang, Anqi.,Zhang, Le.,Guan, Jian.,...&Chen, Yunfa.(2023).Heterojunctioned CuO/Cu 2 O catalyst for highly efficient ozone removal.JOURNAL OF ENVIRONMENTAL SCIENCES,125,340-348.
MLA Ma, Guojun,et al."Heterojunctioned CuO/Cu 2 O catalyst for highly efficient ozone removal".JOURNAL OF ENVIRONMENTAL SCIENCES 125(2023):340-348.
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