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Iron(III)-based ionic liquid-catalyzed regioselective benzylation of arenes and heteroarenes
Gao, Jian1,2; Wang, Jin-Quan3; Song, Qing-Wen1,2; He, Liang-Nian1,2; Gao, J
2011
Source PublicationGREEN CHEMISTRY
ISSN1463-9262
Volume13Issue:5Pages:1182-1186
AbstractAn easily prepared Fe(III)-derived Lewis acid ionic liquid ([C(4)mim][FeCl(4)]), being comprised of 1-butyl-3-methyl imidazolium cation and tetrachloroferrate anion, was found to be an efficient, recyclable catalyst for benzylation of various arenes/heteroarenes into the diarylmethanes derivatives under mild reaction conditions without utilization of additional organic solvent. Interestingly, the acidity of [C(4)mim][FeCl(4)] could account for its catalytic activity in promoting the Lewis acid-catalyzed alkylation. Notably, this type of Fe(III)-based ionic liquid (IL) shows excellent stability, and could be easily recovered, and reused for five times without significant loss of its catalytic activity.
KeywordEfficient Alkylation Alcohols Dodecene Styrenes
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1039/c1gc15056a
Indexed BySCI ; CCR
Language英语
WOS KeywordEFFICIENT ; ALKYLATION ; ALCOHOLS ; DODECENE ; STYRENES
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000290227800022
Citation statistics
Cited Times:49[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/5389
Collection湿法冶金清洁生产技术国家工程实验室
Corresponding AuthorGao, J
Affiliation1.Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
2.Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Gao, Jian,Wang, Jin-Quan,Song, Qing-Wen,et al. Iron(III)-based ionic liquid-catalyzed regioselective benzylation of arenes and heteroarenes[J]. GREEN CHEMISTRY,2011,13(5):1182-1186.
APA Gao, Jian,Wang, Jin-Quan,Song, Qing-Wen,He, Liang-Nian,&Gao, J.(2011).Iron(III)-based ionic liquid-catalyzed regioselective benzylation of arenes and heteroarenes.GREEN CHEMISTRY,13(5),1182-1186.
MLA Gao, Jian,et al."Iron(III)-based ionic liquid-catalyzed regioselective benzylation of arenes and heteroarenes".GREEN CHEMISTRY 13.5(2011):1182-1186.
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