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| Multifunctional polyzwitterion ionic liquid coating for long-lifespan and dendrite-free Zn metal anodes | |
| Lv, Yanqun1,2; Xiao, Ying2; Xu, Shuting3; Huo, Feng3; Chen, Yong2; Zhao, Ming2; Liu, Lili4; Su, Chang1; Zhu, Yanli5; Chen, Shimou2 | |
| 2022-07-26 | |
| Source Publication | JOURNAL OF MATERIALS CHEMISTRY A
 |
| ISSN | 2050-7488 |
| Pages | 10 |
| Abstract | Aqueous zinc (Zn) metal batteries have received widespread attention due to their high safety and environmental friendliness. However, the uncontrollable growth of dendrites, hydrogen evolution reaction, and corrosion severely limit the practical application of aqueous Zn batteries. Herein, a multifunctional water-blocking polyzwitterion ionic liquid coating poly([2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl)-co-tert-butyl acrylate) as the protective layer of the Zn metal anode is proposed to solve these issues. The water-blocking tert-butyl acrylate can prevent water molecules from contacting the Zn metal anode, which plays a key role in inhibiting the hydrogen evolution reaction and corrosion. Meanwhile, zwitterionic ionic liquid moieties are able to tune the solvation environment of the Zn2+ at the electrode/electrolyte interface, inducing compact and planar deposition of the Zn metal. With this synergy effect, the assembled Zn//Zn and Zn//Cu cells achieve a long-term stable plating/stripping performance over 2500 h and a high average coulombic efficiency of 98.6% for 1500 cycles. The Zn//MnO2 and Zn//Mg0.1V2O5 center dot H2O full cells show negligible capacity decay (0.005%) after 4500 cycles. This work provides a new opportunity to protect Zn anodes by water-blocking polyzwitterion ionic liquid coatings in the aqueous electrolyte. |
| DOI | 10.1039/d2ta04779a |
| Language | 英语 |
| WOS Keyword | LITHIUM-METAL |
| Funding Project | National Natural Science Foundation of China[52171198] ; National Natural Science Foundation of China[51922099] ; National Natural Science Foundation of China[52022013] ; Fundamental Research Funds for the Central Universities[buctrc202104] ; Natural Science Foundation of Hebei Province for Distinguished Young Scholars[E2020103052] |
| WOS Research Area | Chemistry ; Energy & Fuels ; Materials Science |
| WOS Subject | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
| Funding Organization | National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Natural Science Foundation of Hebei Province for Distinguished Young Scholars |
| WOS ID | WOS:000837430100001 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/54436 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Su, Chang; Zhu, Yanli; Chen, Shimou |
| Affiliation | 1.Shenyang Univ Chem Technol, Coll Chem Engn, Shenyang, Peoples R China 2.Beijing Univ Chem Technol, Coll Mat Sci & Engn, State Key Lab Chem Resource Engn, Beijing Key Lab Electrochem Proc & Technol Mat, Beijing, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China 4.Beijing Technol & Business Univ, Coll Chem & Mat Engn, Beijing 100048, Peoples R China 5.Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China |
| Recommended Citation GB/T 7714 | Lv, Yanqun,Xiao, Ying,Xu, Shuting,et al. Multifunctional polyzwitterion ionic liquid coating for long-lifespan and dendrite-free Zn metal anodes[J]. JOURNAL OF MATERIALS CHEMISTRY A,2022:10. |
| APA | Lv, Yanqun.,Xiao, Ying.,Xu, Shuting.,Huo, Feng.,Chen, Yong.,...&Chen, Shimou.(2022).Multifunctional polyzwitterion ionic liquid coating for long-lifespan and dendrite-free Zn metal anodes.JOURNAL OF MATERIALS CHEMISTRY A,10. |
| MLA | Lv, Yanqun,et al."Multifunctional polyzwitterion ionic liquid coating for long-lifespan and dendrite-free Zn metal anodes".JOURNAL OF MATERIALS CHEMISTRY A (2022):10. |
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