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| Emerging Strategies for Gel Polymer Electrolytes with Improved Dual-Electrode Side Regulation Mechanisms for Lithium-Sulfur Batteries | |
| Cui, Yingyue1,2,3; Li, Jin1,2,3; Yuan, Xuedi4; Liu, Jiaxin5; Zhang, Haitao1,2,3,6; Wu, Hui1,3; Cai, Yingjun1,3 | |
| 2022-09-22 | |
| Source Publication | CHEMISTRY-AN ASIAN JOURNAL
 |
| ISSN | 1861-4728 |
| Pages | 22 |
| Abstract | Although GPE still has the risk of shuttling due to the incomplete removal of liquid electrolytes compared to SPE, which has the most promise of eliminating polysulfide shuttling, researchers have made abundant efforts to eliminate as much of the polysulfide shuttling effect as possible while retaining the unique advantages of GPE. For example, physical barrier to polysulfides by improving the pore size of GPE or fabricating multidimensional structures by different preparation methods. Further chemical adsorption of polysulfides by adding nanofillers to increase polar sites to create polar-polar interactions with polysulfides or to create Lewis acid-base interactions. However, although chemical adsorption can indeed highly immobilize polysulfides, it still brings disadvantages such as loss of active material. Therefore, other researchers have employed GPE with ion-selective permeability that has electrostatic repulsive force or steric hindrance to polysulfides to better inhibit polysulfide shuttling. However, modifying only the cathode side is not enough to enhance this overall properties of Li-S cells. These problems of poor Li+ transport, lithium dendrite growth, and poor SEI due to uneven lithium ion deposit on Li anode side still affect the overall performance of Li-S cells. Therefore, a GPE to improve these problems on the Li anode side is summarized below. Compared with an all-solid electrolyte, GPE, which has a partially liquid electrolyte, clearly has advantages such as strong interfacial contact, good anode interface compatibility, and high flexibility. However, it is still not comparable to the ionic conductivity, etc. of pure liquid electrolyte only. Therefore, the problems on the lithium metal anode side are mainly focused on the lithium ion transport problems and the problems of lithium dendrite growth and inhomogeneous SEI at the lithium anode interface. Facing the problems in these two aspects, researchers have given many improvement solutions respectively. For the lithium ion transport problem, researchers have instead provided pathways for lithium ion transport by adding amorphous nanofibers or nanofillers to reduce the crystallinity of the polymer and improve the ionic conductivity. Alternatively, the migration number of lithium ions can be increased by limiting the anions in the electrolyte. As for the interfacial problems of lithium anodes, researchers have effectively suppressed the growth of lithium dendrites or inhomogeneous lithium plating/stripping phenomena mainly by adding nanofillers to increase the mechanical strength of GPE or by participating in the generation of SEI. |
| Keyword | gel polymer electrolytes inhibit the "shuttle effect" of polysulfides lithium-sulfur batteries lithium dendrite solid electrolyte interface |
| DOI | 10.1002/asia.202200746 |
| Language | 英语 |
| WOS Keyword | ELECTROCHEMICAL PROPERTIES ; PERFORMANCE ; POLYSULFIDES ; CAPACITY ; SEPARATOR ; PROGRESS ; KINETICS ; ANODE |
| Funding Project | Science and Technology Service Network Initiative program of CAS[KFJ-STS-QYZD2021-02-002] ; Major Program of National Natural Science Foundation of China[21890762] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| Funding Organization | Science and Technology Service Network Initiative program of CAS ; Major Program of National Natural Science Foundation of China |
| WOS ID | WOS:000858095600001 |
| Publisher | WILEY-V C H VERLAG GMBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/54676 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Cai, Yingjun |
| Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Beijing 100049, Peoples R China 4.Zhengzhou Inst Emerging Ind Technol, Henan Key Lab Energy Storage Mat & Proc, Zhengzhou 450003, Peoples R China 5.Zhengzhou Univ, Sch Henan Inst Adv Technol, Zhengzhou 450002, Peoples R China 6.Shenyang Univ Chem Technol, Coll Chem Engn, Shenyang 110142, Peoples R China |
| Recommended Citation GB/T 7714 | Cui, Yingyue,Li, Jin,Yuan, Xuedi,et al. Emerging Strategies for Gel Polymer Electrolytes with Improved Dual-Electrode Side Regulation Mechanisms for Lithium-Sulfur Batteries[J]. CHEMISTRY-AN ASIAN JOURNAL,2022:22. |
| APA | Cui, Yingyue.,Li, Jin.,Yuan, Xuedi.,Liu, Jiaxin.,Zhang, Haitao.,...&Cai, Yingjun.(2022).Emerging Strategies for Gel Polymer Electrolytes with Improved Dual-Electrode Side Regulation Mechanisms for Lithium-Sulfur Batteries.CHEMISTRY-AN ASIAN JOURNAL,22. |
| MLA | Cui, Yingyue,et al."Emerging Strategies for Gel Polymer Electrolytes with Improved Dual-Electrode Side Regulation Mechanisms for Lithium-Sulfur Batteries".CHEMISTRY-AN ASIAN JOURNAL (2022):22. |
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