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Characteristics of fused calcium magnesium phosphate fertilizer (FCMP) made from municipal sewage sludge and its properties | |
Qin, Pengfei1,2; Hui, Helong1; Song, Wenli1,2; Wu, Hao2,3; Li, Songgeng1,2,4 | |
2022-12-01 | |
Source Publication | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
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ISSN | 2213-2929 |
Volume | 10Issue:6Pages:8 |
Abstract | A high P-availability glass phosphate fertilizer was manufactured from municipal sewage sludge ash (SSA) in reference to the conventional method for fused calcium magnesium phosphate fertilizer (FCMP). P-availability in SSA-made FCMP was examined by varying the amount of alkali earth metals (MO, CaO and MgO) addition in the FCMP. Various techniques such as XRD, FTIR, Raman, Mo spexpressioncing diexpressioneresis ssbauer spectra and Al-27 MAS NMR spectra were applied to examine the FCMP structure made from SSA. It was found that the silicate glass network depoly-merization due to MO addition is the main cause of P-availability improvement. MgO was more effective than CaO. Special attention was paid to Fe and Al, which is considered the main cause for the difference from conventional FCMP formular. Fe and Al in the silicate-phosphate glass structure can be taken either as a glass network modifier or as a network former, depending on the amount of MO added. Cooling rate effect on P -availability was also discussed. The heavy metal contents in the SSA-made FCMP meet the requirement for agriculture use. |
Keyword | Sewage sludge ash MgO CaO Phosphorus Glass fertilizer |
DOI | 10.1016/j.jece.2022.108563 |
Language | 英语 |
WOS Keyword | PHOSPHORUS RECOVERY ; SILICATE-GLASSES ; ASH ; RAMAN ; CRYSTALLIZATION ; BIOACTIVITY ; MANAGEMENT ; STATE ; NMR |
Funding Project | Chinese Academy of Sciences[XDA23030301] ; Sichuan Science and Technology Program of China[2022YFSY0039] |
WOS Research Area | Engineering |
WOS Subject | Engineering, Environmental ; Engineering, Chemical |
Funding Organization | Chinese Academy of Sciences ; Sichuan Science and Technology Program of China |
WOS ID | WOS:000861061500002 |
Publisher | ELSEVIER SCI LTD |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/54808 |
Collection | 中国科学院过程工程研究所 |
Corresponding Author | Li, Songgeng |
Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sino Danish Coll, Sino Danish Ctr Educ & Res, Beijing, Peoples R China 3.Tech Univ Denmark, Dept Chem & Biochem Engn, DK-2800 Lyngby, Denmark 4.Univ Chinese Acad Sci, Sch Chem Engn, Beijing, Peoples R China |
Recommended Citation GB/T 7714 | Qin, Pengfei,Hui, Helong,Song, Wenli,et al. Characteristics of fused calcium magnesium phosphate fertilizer (FCMP) made from municipal sewage sludge and its properties[J]. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,2022,10(6):8. |
APA | Qin, Pengfei,Hui, Helong,Song, Wenli,Wu, Hao,&Li, Songgeng.(2022).Characteristics of fused calcium magnesium phosphate fertilizer (FCMP) made from municipal sewage sludge and its properties.JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,10(6),8. |
MLA | Qin, Pengfei,et al."Characteristics of fused calcium magnesium phosphate fertilizer (FCMP) made from municipal sewage sludge and its properties".JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 10.6(2022):8. |
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