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硫代磷酸/伯胺N_(1923)协同萃取锌和镉的机理
张大力; 柯家骏; 卢立柱
2003
Source Publication过程工程学报
Issue04Pages:313-316
Abstract有机硫代磷酸/伯胺N_(1923)协同萃取锌、镉的萃取率随pH的变化较为反常,可能因伯胺N_(1923)与硫酸作用进而聚力反向胶束。实验表明,如以(N_(1923))_n·H_2SO_4表示反向胶束的实验式,N_(1923)与H_2SO_4比值n多为3左右,可能与空间效应相关。萃取机理为: M~(2+)_(a)~(2+)+2BHA_(o)+(2/n)SO_4~(2-)_(a)=MA_(2(o))+(2/n)(B_n·H_2SO_4)_(o)+2(1-2/n)H~+_(a),n=3,4,5。
Keyword有机硫代磷酸 伯胺n_(1923) 溶剂萃取 反向胶束
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/5483
Collection研究所(批量导入)
Recommended Citation
GB/T 7714
张大力,柯家骏,卢立柱. 硫代磷酸/伯胺N_(1923)协同萃取锌和镉的机理[J]. 过程工程学报,2003(04):313-316.
APA 张大力,柯家骏,&卢立柱.(2003).硫代磷酸/伯胺N_(1923)协同萃取锌和镉的机理.过程工程学报(04),313-316.
MLA 张大力,et al."硫代磷酸/伯胺N_(1923)协同萃取锌和镉的机理".过程工程学报 .04(2003):313-316.
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