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Rare-earth separations enhanced by magnetic field | |
Fan, Bangyu1,2,3,4; Li, Fujian1,2,3; Cheng, Yanyan1,2,3; Wang, Zhongzhi1,2,3; Zhang, Nian1,2,3,4; Wu, Qingrong1,2; Bai, Lu1,2,3; Zhang, Xiangping1,2,3 | |
2022-11-15 | |
Source Publication | SEPARATION AND PURIFICATION TECHNOLOGY
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ISSN | 1383-5866 |
Volume | 301Pages:9 |
Abstract | The separation of rare earth (RE) elements is a challenge from their discovery to the present day, due to the chemical and physical similarities as a group. The intrinsic properties of REs are basic for separation mechanisms. Due to the large difference in magnetic moment, a new method of selected crystallization enhanced by magnetic field was developed to separate REs efficiently, at room temperature and pressure without complex equipment. An experimental proof of concept is provided for the binary systems RE2(SO4)3-Lu2(SO4)3 (RE = Gd, Nd, Tb, Dy or Ho). This magnetic separation process increases the separation factors of Gd(III)/Lu(III) from their mixture by 39% in kinetics, but similar in or near thermodynamic equilibrium without magnetic field. The beta RE/Lu (RE = Gd, Nd, Tb, Dy or Ho) were promoted by 17%-47% with permanent magnet, increasing with raising of the applied magnetic field strength. A process based on magnetic moment difference is a potential alternative method for rare-earth separations, with low energy consumption and high efficiency in the presence of an external magnetic field. |
Keyword | Rare earth element Different magnetic moment Crystallization separation Magnetic field |
DOI | 10.1016/j.seppur.2022.122025 |
Language | 英语 |
WOS Keyword | ZUR TRENNUNG ; IONS |
Funding Project | National Natural Science Foundation of China[IAGM2020DB03] ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences[E055A002] ; Self-deployed Projects of Ganjiang Innovation Academy, Chinese Academy of Sciences[ZDRW-CN-2021-3-2)] ; Key Research Program of the Chinese Academy of Sciences[JXUST-XTCX-2022-01] ; Special Research Assistant Project of the Chinese Academy of Sciences ; Ministry of Education and Jiangxi Province, Jiangxi University of Science and Technology ; [22008244] |
WOS Research Area | Engineering |
WOS Subject | Engineering, Chemical |
Funding Organization | National Natural Science Foundation of China ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences ; Self-deployed Projects of Ganjiang Innovation Academy, Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; Special Research Assistant Project of the Chinese Academy of Sciences ; Ministry of Education and Jiangxi Province, Jiangxi University of Science and Technology |
WOS ID | WOS:000868915200005 |
Publisher | ELSEVIER |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/55225 |
Collection | 中国科学院过程工程研究所 |
Corresponding Author | Li, Fujian; Zhang, Xiangping |
Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Ganjiang Innovat Acad, Ganzhou 341000, Peoples R China 4.Nanchang Univ, Sch Chem & Chem Engn, Nanchang 330031, Peoples R China |
Recommended Citation GB/T 7714 | Fan, Bangyu,Li, Fujian,Cheng, Yanyan,et al. Rare-earth separations enhanced by magnetic field[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2022,301:9. |
APA | Fan, Bangyu.,Li, Fujian.,Cheng, Yanyan.,Wang, Zhongzhi.,Zhang, Nian.,...&Zhang, Xiangping.(2022).Rare-earth separations enhanced by magnetic field.SEPARATION AND PURIFICATION TECHNOLOGY,301,9. |
MLA | Fan, Bangyu,et al."Rare-earth separations enhanced by magnetic field".SEPARATION AND PURIFICATION TECHNOLOGY 301(2022):9. |
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