Knowledge Management System Of Institute of process engineering,CAS
| Ultrahigh Mass Activity for the Hydrogen Evolution Reaction by Anchoring Platinum Single Atoms on Active {100} Facets of TiC via Cation Defect Engineering | |
| Dong, Qinghua1; Ma, Sugang1; Zhu, Jiuyi1; Yue, Fen1; Geng, Yuqi1; Zheng, Jie1; Ge, Yu1; Fan, Chuanlin1,2; Zhang, Huigang1,2; Xiang, Maoqiao1,2,3; Zhu, Qingshan1,2,3 | |
| 2022-11-07 | |
| Source Publication | ADVANCED FUNCTIONAL MATERIALS
 |
| ISSN | 1616-301X |
| Pages | 10 |
| Abstract | Improving the platinum (Pt) mass activity for low-cost electrochemical hydrogen evolution is an important and arduous task. Here, a selective etching-reducing fluidized bed reactor technique is reported to create Ti vacancies and firmly anchor single Pt atoms on the active {100} facets of titanium carbide (TiC) to increase the Pt utilization efficiency and improve catalytic activity significantly by a synergistic effect between Ti vacancies and Pt atoms. The generated Ti vacancies are negatively charged and stabilize Pt atoms by forming covalent Pt-C bonds, showing excellent long-term durability. Pt single atoms (ultralow load of 1.2 mu g cm(-2)) on the defective TiC {100} show remarkable activity (24.9 mV at 10 mA cm(-2)) and a mass activity (49.69 A mg(-1)) approximate to 190 times that of the state-of-the-art Pt-C catalyst and nearly double the previously reported best values. The developed cation defect engineering exhibits excellent potential for fabricating next-generation advanced single-atom catalysts for large-scale hydrogen evolution at a low cost. |
| Keyword | cation titanium defect fluidized bed reactor hydrogen evolution reactions platinum single atoms ultrahigh mass activity |
| DOI | 10.1002/adfm.202210665 |
| Language | 英语 |
| WOS Keyword | TITANIUM CARBIDE ; METAL CARBIDES ; CATALYSTS ; ELECTROCATALYST ; OXIDATION ; CLUSTERS ; POWDERS |
| Funding Project | Basic Frontier Scientific Research of the Chinese Academy of Sciences[ZDBS-LY-JSC041] ; Scientific Instrument Developing Project of the Chinese Academy of Sciences[YJKYYQ20210043] ; National Natural Science Foundation of China[22178348] ; Youth Innovation Promotion Association CAS[292021000085] |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| WOS Subject | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| Funding Organization | Basic Frontier Scientific Research of the Chinese Academy of Sciences ; Scientific Instrument Developing Project of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; Youth Innovation Promotion Association CAS |
| WOS ID | WOS:000879670100001 |
| Publisher | WILEY-V C H VERLAG GMBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/55588 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Xiang, Maoqiao; Zhu, Qingshan |
| Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | Dong, Qinghua,Ma, Sugang,Zhu, Jiuyi,et al. Ultrahigh Mass Activity for the Hydrogen Evolution Reaction by Anchoring Platinum Single Atoms on Active {100} Facets of TiC via Cation Defect Engineering[J]. ADVANCED FUNCTIONAL MATERIALS,2022:10. |
| APA | Dong, Qinghua.,Ma, Sugang.,Zhu, Jiuyi.,Yue, Fen.,Geng, Yuqi.,...&Zhu, Qingshan.(2022).Ultrahigh Mass Activity for the Hydrogen Evolution Reaction by Anchoring Platinum Single Atoms on Active {100} Facets of TiC via Cation Defect Engineering.ADVANCED FUNCTIONAL MATERIALS,10. |
| MLA | Dong, Qinghua,et al."Ultrahigh Mass Activity for the Hydrogen Evolution Reaction by Anchoring Platinum Single Atoms on Active {100} Facets of TiC via Cation Defect Engineering".ADVANCED FUNCTIONAL MATERIALS (2022):10. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment