Study on the phosphate removal from aqueous solution using modified fly ash | |
Xu, Ke1; Deng, Tong2; Liu, Juntan1; Peng, Weigong1; Xu, K | |
2010-12-01 | |
Source Publication | FUEL
![]() |
ISSN | 0016-2361 |
Volume | 89Issue:12Pages:3668-3674 |
Abstract | In this work the fly ash was modified by sulfuric acid for the removal of phosphate. It was found that modification of fly ash could significantly enhance the phosphate immobilization ability of the fly ash. The specific surface area of the fly ash increased from 8.8 to 32.5 m(2)/g after treated with sulfuric acid. The modification of the fly ash also resulted in the mobilization of acid-soluble metal ions due to partial or complete dissolution of the metals under the acidic conditions. Both adsorption and precipitation contributed to the removal of phosphate by the modified fly ash but precipitation was a major mechanism of phosphate removal. The experimental results showed that adsorption of phosphate by the modified fly ash was rapid, the removal percentage of phosphate could reach maximum in 5 min. In the range of 5-9, pH did not significantly affect the removal of phosphate and the removal percentage of phosphate increased with the increase of adsorbent dosage. The adsorption of phosphate by the modified fly ash could be described well by Langmuir isotherm equation, the Langmuir constant Q(0) was 9.15 mg g (1). The XRD patterns and the SEM images of modified fly ash after sorption revealed that CaHPO(4)center dot 2H(2)O was formed in the removal of phosphate. In addition, phosphate also formed precipitate with aluminum and iron. (C) 2010 Elsevier Ltd. All rights reserved. |
Keyword | Fly Ash Modification Sulfuric Acid Phosphate Removal |
Subtype | Article |
WOS Headings | Science & Technology ; Technology |
DOI | 10.1016/j.fuel.2010.07.034 |
Indexed By | SCI |
Language | 英语 |
WOS Keyword | CONSTRUCTED WETLAND SYSTEMS ; IMMOBILIZATION ; SLAG |
WOS Research Area | Energy & Fuels ; Engineering |
WOS Subject | Energy & Fuels ; Engineering, Chemical |
WOS ID | WOS:000282086200009 |
Citation statistics | |
Document Type | 期刊论文 |
Version | 出版稿 |
Identifier | http://ir.ipe.ac.cn/handle/122111/5559 |
Collection | 湿法冶金清洁生产技术国家工程实验室 |
Corresponding Author | Xu, K |
Affiliation | 1.Zhengzhou Inst Aeronaut Ind Management, Zhengzhou 450015, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China |
Recommended Citation GB/T 7714 | Xu, Ke,Deng, Tong,Liu, Juntan,et al. Study on the phosphate removal from aqueous solution using modified fly ash[J]. FUEL,2010,89(12):3668-3674. |
APA | Xu, Ke,Deng, Tong,Liu, Juntan,Peng, Weigong,&Xu, K.(2010).Study on the phosphate removal from aqueous solution using modified fly ash.FUEL,89(12),3668-3674. |
MLA | Xu, Ke,et al."Study on the phosphate removal from aqueous solution using modified fly ash".FUEL 89.12(2010):3668-3674. |
Files in This Item: | ||||||
File Name/Size | DocType | Version | Access | License | ||
20131111-1095-复件 1-s(726KB) | 限制开放 | CC BY-NC-SA | Application Full Text |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment