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A Sustainable Low-Temperature Roasting and Water Leaching Process for Simultaneously Extracting Mn, Cu, Co, and Ni from Ocean Manganese Nodules
Ju, Jinrong1,2,3; Feng, Yali1; Li, Haoran2,3; Ma, Ruiyu1; Wang, Ben1
2022-11-15
Source PublicationJOURNAL OF SUSTAINABLE METALLURGY
ISSN2199-3823
Pages13
AbstractOcean manganese nodules are rich in Mn, and also contain the strategic metals Cu, Co, and Ni. In this study, a sustainable low-temperature roasting and water leaching process for simultaneously extracting Mn, Cu, Co, and Ni from ocean manganese nodules was proposed. The results show that the primary mineral phase of iron-manganese oxides in the ocean manganese nodules reacted with ammonium sulfate during the roasting process, converting it to (NH4)(2)Mn-2(SO4)(3) , MnSO4, and NH4Fe(SO4)(2) . As the primary mineral phase was destroyed, Cu, Co, and Ni dispersed in the other host minerals could be released to react with ammonium sulfate and form metal sulfates. The sulfation reaction was completed at the roasting temperature of 380 degrees C, the mass ratio of ammonium sulfate to ocean manganese nodules of 1.25:1, and the roasting time of 90 min. The roasted slag was then leached with pure water and the leaching efficiencies for Mn, Cu, Co, and Ni reached 95.87%, 83.53%, 75.02%, and 87.04% under the liquid-to-solid ratio of 5:1, the leaching temperature of 40 degrees C, and leaching time of 30 min. The ammonium sulfate roasting-water leaching technology is a promising process, and the roasting temperature of 380 degrees C is much lower than that of pyrometallurgical techniques proposed in other studies, resulting in significant energy savings for the process. [GRAPHICS] .
KeywordOcean manganese nodules Ammonium sulfate roasting Water leaching Valuable metals Mineral phase conversion
DOI10.1007/s40831-022-00623-8
Language英语
WOS KeywordAMMONIUM-SULFATE ; PHASE-TRANSFORMATION ; VALUABLE METALS ; NICKEL ; COPPER ; MECHANISM ; COBALT ; ORE ; GEOCHEMISTRY ; TRANSECT
Funding ProjectChina Ocean Mineral Resources RD Association[JS-KTHT-2019-01]
WOS Research AreaScience & Technology - Other Topics ; Metallurgy & Metallurgical Engineering
WOS SubjectGreen & Sustainable Science & Technology ; Metallurgy & Metallurgical Engineering
Funding OrganizationChina Ocean Mineral Resources RD Association
WOS IDWOS:000884178900001
PublisherSPRINGER
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/55632
Collection中国科学院过程工程研究所
Corresponding AuthorJu, Jinrong; Feng, Yali
Affiliation1.Univ Sci & Technol Beijing, Civil & Resource Engn Sch, Beijing 100083, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Key Lab Biochem Engn, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Ju, Jinrong,Feng, Yali,Li, Haoran,et al. A Sustainable Low-Temperature Roasting and Water Leaching Process for Simultaneously Extracting Mn, Cu, Co, and Ni from Ocean Manganese Nodules[J]. JOURNAL OF SUSTAINABLE METALLURGY,2022:13.
APA Ju, Jinrong,Feng, Yali,Li, Haoran,Ma, Ruiyu,&Wang, Ben.(2022).A Sustainable Low-Temperature Roasting and Water Leaching Process for Simultaneously Extracting Mn, Cu, Co, and Ni from Ocean Manganese Nodules.JOURNAL OF SUSTAINABLE METALLURGY,13.
MLA Ju, Jinrong,et al."A Sustainable Low-Temperature Roasting and Water Leaching Process for Simultaneously Extracting Mn, Cu, Co, and Ni from Ocean Manganese Nodules".JOURNAL OF SUSTAINABLE METALLURGY (2022):13.
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