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Recovery of Vanadium, Titanium, and Iron from Vanadium Titanomagnetite Concentrate Through Ammonium Sulfate Cascade Roasting with Potassium Pyrosulfate
Bian, Zhenzhong1; Ning, Zhangxuan1; Zhao, Kai1; Gao, Rui1; Li, Wenzheng1; Lv, Chao1; Yuan, Yu1; Li, Haoran2
2022-11-22
Source PublicationJOURNAL OF SUSTAINABLE METALLURGY
ISSN2199-3823
Pages13
AbstractIn this study, an efficient utilization of vanadium titanomagnetite concentrate was systemically investigated through potassium pyrosulfate (K2S2O7) synergized with ammonium sulfate ((NH4)(2)SO4) cascade roasting to separate and recover vanadium, iron, and titanium. The result shows that 95.87% of vanadium and 80.13% of iron could be extracted, while that of titanium was only 9.68% under the condition of first-order temperature and time 240 degrees C and 3 h, second-order temperature and time 410 degrees C and 2 h, and the mass ratio of K2S2O7, (NH4)(2)SO4 and PVBT 0.1:4:1. Phase transformation and thermodynamic analysis reveals that the valuable metals could be converted into corresponding sulfates in situ. XRD and SEM-EDS show that the addition of K2S2O7 strongly promoted the formation of liquid phase and soluble potassium vanadate. A high-titanium slag with 85.32% titanium was obtained by the iron powder induction leaching and alkali leaching. Additionally, the additive (NH4)(2)SO4 could be recycled, achieving zero emission of waste gas. [GRAPHICS] .
KeywordVanadium titanomagnetite concentrate Ammonium sulfate Potassium pyrosulfate Cascade roasting Valuable metals
DOI10.1007/s40831-022-00627-4
Language英语
WOS KeywordBLAST-FURNACE SLAG ; VALUABLE METALS ; EXTRACTION ; MECHANISM ; DECOMPOSITION ; MAGNETITE ; ILMENITE ; ACID
Funding ProjectKey Research and Development Program of Shanxi Province[201903D121070] ; Fundamental Research Program of Shanxi Province ; Shanxi Datong University Doctoral Research Startup Fund Project
WOS Research AreaScience & Technology - Other Topics ; Metallurgy & Metallurgical Engineering
WOS SubjectGreen & Sustainable Science & Technology ; Metallurgy & Metallurgical Engineering
Funding OrganizationKey Research and Development Program of Shanxi Province ; Fundamental Research Program of Shanxi Province ; Shanxi Datong University Doctoral Research Startup Fund Project
WOS IDWOS:000886451100001
PublisherSPRINGER
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Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/55671
Collection中国科学院过程工程研究所
Corresponding AuthorBian, Zhenzhong; Zhao, Kai
Affiliation1.Shanxi Datong Univ, Coll Coal Engn, Datong 037009, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Bian, Zhenzhong,Ning, Zhangxuan,Zhao, Kai,et al. Recovery of Vanadium, Titanium, and Iron from Vanadium Titanomagnetite Concentrate Through Ammonium Sulfate Cascade Roasting with Potassium Pyrosulfate[J]. JOURNAL OF SUSTAINABLE METALLURGY,2022:13.
APA Bian, Zhenzhong.,Ning, Zhangxuan.,Zhao, Kai.,Gao, Rui.,Li, Wenzheng.,...&Li, Haoran.(2022).Recovery of Vanadium, Titanium, and Iron from Vanadium Titanomagnetite Concentrate Through Ammonium Sulfate Cascade Roasting with Potassium Pyrosulfate.JOURNAL OF SUSTAINABLE METALLURGY,13.
MLA Bian, Zhenzhong,et al."Recovery of Vanadium, Titanium, and Iron from Vanadium Titanomagnetite Concentrate Through Ammonium Sulfate Cascade Roasting with Potassium Pyrosulfate".JOURNAL OF SUSTAINABLE METALLURGY (2022):13.
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