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| Cooperative catalytic effects between the penta-coordinated Al and Al2O3 in Al2O3-AlPO4 for aldol condensation of methyl acetate with formaldehyde to methyl acrylate | |
| Wu, Zhenyu1,2; Li, Zengxi1,2; Li, Chunshan1,2,3 | |
| 2022-12-01 | |
| Source Publication | CHINESE JOURNAL OF CHEMICAL ENGINEERING
 |
| ISSN | 1004-9541 |
| Volume | 52Pages:172-183 |
| Abstract | The bare amorphous Al2O3-AlPO4 and Cs/Al2O3-AlPO4 catalysts were developed for the aldol condensa-tion of methyl acetate with formaldehyde to methyl acrylate. The structure and property of catalyst were characterized by XRD, XPS, BET, Pyridine-IR, FT-IR, 27Al-MASNMR, NH3-/CO2-TPD and SEM. The correla-tion between structural features and acid-base properties was established, and the loading effect of the cesium species was investigated. Due to cooperative catalytic effects between the penta-coordinated Al and Al2O3, the weak-II acid and medium acid site densities and the product selectivity were improved. While the basic site densities of these catalysts were almost in proportion to the conversion of methyl acetate. The loaded Cs could form new basic sites and change the distribution of acid sites which further enhance the catalytic performance. As a result, the 10Cs/8AlP was proved to be an optimal catalyst with the yield and selectivity of 21.2% and 85% for methyl acrylate respectively. During the reaction, a deac-tivation behavior was observed on 10Cs/8AlP catalyst due to the carbon deposition, however, it could be regenerated by thermal treatment in the air atmosphere at 400 degrees C.(c) 2022 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd. All rights reserved. |
| Keyword | Methyl acrylate (MA) Aldol condensation Penta-coordinated aluminum Cooperative effects |
| DOI | 10.1016/j.cjche.2021.11.025 |
| Language | 英语 |
| WOS Keyword | METAL-SUPPORT INTERACTION ; ALUMINUM PHOSPHATE ; MESOPOROUS ALPO4 ; CESIUM OXIDE ; PHASE ; OXIDATION ; METHANOL ; ZEOLITE ; ACID ; DEHYDRATION |
| Funding Project | Key Research Program of Frontier Sciences[QYZDB-SSW-SLH022] ; National Natural Science Foundation of China[21676270] ; National Natural Science Foundation of China[21878293] ; National Natural Science Foundation of China[22178338] ; Joint Fund of the Yulin University ; Dalian National-Laboratory for Clean Energy[2021018] ; Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering[2017-K08] |
| WOS Research Area | Engineering |
| WOS Subject | Engineering, Chemical |
| Funding Organization | Key Research Program of Frontier Sciences ; National Natural Science Foundation of China ; Joint Fund of the Yulin University ; Dalian National-Laboratory for Clean Energy ; Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering |
| WOS ID | WOS:000902231800014 |
| Publisher | CHEMICAL INDUSTRY PRESS CO LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/56326 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Li, Zengxi; Li, Chunshan |
| Affiliation | 1.Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Beijing Key Lab Ion Liq, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Zhongke Langfang Inst Proc Engn, Shijiazhuang 065000, Hebei, Peoples R China |
| Recommended Citation GB/T 7714 | Wu, Zhenyu,Li, Zengxi,Li, Chunshan. Cooperative catalytic effects between the penta-coordinated Al and Al2O3 in Al2O3-AlPO4 for aldol condensation of methyl acetate with formaldehyde to methyl acrylate[J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING,2022,52:172-183. |
| APA | Wu, Zhenyu,Li, Zengxi,&Li, Chunshan.(2022).Cooperative catalytic effects between the penta-coordinated Al and Al2O3 in Al2O3-AlPO4 for aldol condensation of methyl acetate with formaldehyde to methyl acrylate.CHINESE JOURNAL OF CHEMICAL ENGINEERING,52,172-183. |
| MLA | Wu, Zhenyu,et al."Cooperative catalytic effects between the penta-coordinated Al and Al2O3 in Al2O3-AlPO4 for aldol condensation of methyl acetate with formaldehyde to methyl acrylate".CHINESE JOURNAL OF CHEMICAL ENGINEERING 52(2022):172-183. |
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