Knowledge Management System Of Institute of process engineering,CAS
| Preliminary exploration of the reactor configuration for hydroformylation of 1-dodecene catalyzed by water soluble rhodium complex | |
| Alternative Title | Chin. J. Chem. Eng. |
| Mao, ZS; Bi, XY; Yu, GZ; Zhang, YQ; Yang, C; Wang, R | |
| 2002-02-01 | |
| Source Publication | CHINESE JOURNAL OF CHEMICAL ENGINEERING
 |
| ISSN | 1004-9541 |
| Volume | 10Issue:1Pages:45-51 |
| Abstract | Hydroformylation of 1-dodecene was studied in a biphasic system using water-soluble rhodium complex [RhCl(CO)(TPPTS)(2)] as catalyst in the presence of cetyl trimethyl ammonium bromide as surfactant to enhance the reaction rate. Efforts were devoted to improve the performance of hydroformylation by exploring reactor configuration which enhanced the mixing, dispersion and interphase mass transfer. Experiments were carried out in a 0.5 L autoclave at the total pressure of 1.1 MPa and temperature from 363 K to 373 K. Several surface aeration configurations were tested, and higher hydroformylation rate with higher normal/branched aldehyde ratio produced were achieved. The experiences suggest that improved reactor configuration by taking reaction engineering measures is beneficial to better process economy in alkene hydroformylation.; Hydroformylation of 1-dodecene was studied in a biphasic system using water-soluble rhodium complex [RhCl(CO)(TPPTS)(2)] as catalyst in the presence of cetyl trimethyl ammonium bromide as surfactant to enhance the reaction rate. Efforts were devoted to improve the performance of hydroformylation by exploring reactor configuration which enhanced the mixing, dispersion and interphase mass transfer. Experiments were carried out in a 0.5 L autoclave at the total pressure of 1.1 MPa and temperature from 363 K to 373 K. Several surface aeration configurations were tested, and higher hydroformylation rate with higher normal/branched aldehyde ratio produced were achieved. The experiences suggest that improved reactor configuration by taking reaction engineering measures is beneficial to better process economy in alkene hydroformylation. |
| Keyword | 1-dodecene Biphasic Hydroformylation Gas-liquid-liquid Reactor Reaction Engineering Surface Aeration Emulsification N/i Ratio |
| Subtype | Article |
| WOS Headings | Science & Technology ; Technology |
| URL | 查看原文 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Research Area | Engineering |
| WOS Subject | Engineering, Chemical |
| WOS ID | WOS:000174602500006 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Version | 出版稿 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/5634 |
| Collection | 研究所（批量导入） |
| Affiliation | Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China |
| Recommended Citation GB/T 7714 | Mao, ZS,Bi, XY,Yu, GZ,et al. Preliminary exploration of the reactor configuration for hydroformylation of 1-dodecene catalyzed by water soluble rhodium complex[J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING,2002,10(1):45-51. |
| APA | Mao, ZS,Bi, XY,Yu, GZ,Zhang, YQ,Yang, C,&Wang, R.(2002).Preliminary exploration of the reactor configuration for hydroformylation of 1-dodecene catalyzed by water soluble rhodium complex.CHINESE JOURNAL OF CHEMICAL ENGINEERING,10(1),45-51. |
| MLA | Mao, ZS,et al."Preliminary exploration of the reactor configuration for hydroformylation of 1-dodecene catalyzed by water soluble rhodium complex".CHINESE JOURNAL OF CHEMICAL ENGINEERING 10.1(2002):45-51. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| PreliminaryExplo_省略_（403KB） | 限制开放 | CC BY-NC-SA | Application Full Text | |||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment