Knowledge Management System Of Institute of process engineering,CAS
| Facilitating uniform lithium deposition via nanoconfinement of free amide molecules in solid electrolyte complexion for lithium metal batteries | |
| Wang, Simeng1,2; Chen, Yong1,3; Fang, Qiu4,5; Huang, Jiajia1,2; Wang, Xuefeng4,5; Chen, Shimou6; Zhang, Suojiang1,2 | |
| 2023 | |
| Source Publication | ENERGY STORAGE MATERIALS
 |
| ISSN | 2405-8297 |
| Volume | 54Pages:596-604 |
| Abstract | As a facile method to facilitate the uniform lithium deposition on the lithium metal anode, a unique solid electrolyte complexion consisted of polyethylene oxide, UiO-66-NH2, and deep eutectic solvents (PEMD) with nanoconfinement significantly improves the lithium metal cycling stability. Specifically, the free amide molecules of deep eutectic solvents are nanoconfined by UiO-66-NH2 in the polyethylene oxide (PEO) matrix, and an excellent symmetrical electrochemical cycling performance more than 3600 h is achieved, extended by similar to 10 times comparing to the reference. Furthermore, the Li || PEMD || LiFePO4 cell not only exhibits satisfactory electrochemical performance at 60 degrees C inherited from PEO, but also presents unexpected capacity reversibility, cycling stability, and enhanced rate capability at low temperatures down to 10 degrees C. The design of the solid electrolyte complexion with nanoconfinement opens an innovative avenue to the practical implementation of the PEO based lithium metal batteries. |
| Keyword | Solid electrolyte complexion Nanoconfinement Uniform lithium deposition Deep eutectic solvents Lithium metal batteries |
| DOI | 10.1016/j.ensm.2022.11.002 |
| Language | 英语 |
| WOS Keyword | EUTECTIC SOLVENTS DESS ; DENDRITE-FREE ; POLYMER ELECTROLYTES ; N-METHYLACETAMIDE ; DEPENDENCE ; TRANSPORT ; DESIGN ; MATRIX ; SAFE ; SALT |
| Funding Project | National Key Research and Development Program of China[2021YFB2400300] ; Key Research and Development Program of Henan Province[221111240100] ; Science Fund for Creative Research Groups of the National Natural Science Foundation of China[21921005] ; IPE Talent Start-up Program of Institute of Process Engineering of Chinese Academy of Sciences[E0293507] ; National Natural Science Foundation of China (NSFC)[22005334] ; Natural Science Foundation of Beijing[Z200013] |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| WOS Subject | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| Funding Organization | National Key Research and Development Program of China ; Key Research and Development Program of Henan Province ; Science Fund for Creative Research Groups of the National Natural Science Foundation of China ; IPE Talent Start-up Program of Institute of Process Engineering of Chinese Academy of Sciences ; National Natural Science Foundation of China (NSFC) ; Natural Science Foundation of Beijing |
| WOS ID | WOS:000905491300001 |
| Publisher | ELSEVIER |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/56523 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Huang, Jiajia; Wang, Xuefeng; Zhang, Suojiang |
| Affiliation | 1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, CAS Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China 3.China Univ Min & Technol, Sch Chem & Environm Engn, Beijing 100083, Peoples R China 4.Chinese Acad Sci, Inst Phys, Lab Adv Mat & Electron Microscopy, Beijing 100190, Peoples R China 5.Tianmu Lake Inst Adv Energy Storage Technol Co Lt, Liyang 213300, Jiangsu, Peoples R China 6.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China |
| Recommended Citation GB/T 7714 | Wang, Simeng,Chen, Yong,Fang, Qiu,et al. Facilitating uniform lithium deposition via nanoconfinement of free amide molecules in solid electrolyte complexion for lithium metal batteries[J]. ENERGY STORAGE MATERIALS,2023,54:596-604. |
| APA | Wang, Simeng.,Chen, Yong.,Fang, Qiu.,Huang, Jiajia.,Wang, Xuefeng.,...&Zhang, Suojiang.(2023).Facilitating uniform lithium deposition via nanoconfinement of free amide molecules in solid electrolyte complexion for lithium metal batteries.ENERGY STORAGE MATERIALS,54,596-604. |
| MLA | Wang, Simeng,et al."Facilitating uniform lithium deposition via nanoconfinement of free amide molecules in solid electrolyte complexion for lithium metal batteries".ENERGY STORAGE MATERIALS 54(2023):596-604. |
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