Knowledge Management System Of Institute of process engineering,CAS
| Kinetics of hydroformylation of propylene using RhCl(CO)(TPPTS)(2)/TPPTS complex catalyst in aqueous system | |
| Alternative Title | Catal. Today |
| Yang, C; Mao, ZS; Wang, YF; Chen, JY | |
| 2002-05-15 | |
| Source Publication | CATALYSIS TODAY
 |
| ISSN | 0920-5861 |
| Volume | 74Issue:1-2Pages:111-119 |
| Abstract | The kinetics of RhCl(CO)(TPPTS)(2)/TPPTS catalyzed hydroformylation of propylene was studied by an orthogonal experimental design. The hydroformylation reaction was carried out batchwise in a 500 ml stirred autoclave. The effects of temperature, total pressure, molar ratio of hydrogen/carbon monoxide, partial pressure of propylene, molar ratio of rhodium/TPPTS and concentration of rhodium catalyst on the initial rate of reaction were determined by margin and variance analysis. Several empirical rate equations were proposed to represent the experimental data. The kinetic parameters were evaluated and the activation energy was found in the range of 75 similar to 85 kJ/mol. The regioselectivity of hydroformylation was also determined and the molar ratio of normal/isomeric aldehyde varied from 3.9 to 56.1. 2002 Elsevier Science B.V. (C) All rights reserved.; The kinetics of RhCl(CO)(TPPTS)(2)/TPPTS catalyzed hydroformylation of propylene was studied by an orthogonal experimental design. The hydroformylation reaction was carried out batchwise in a 500 ml stirred autoclave. The effects of temperature, total pressure, molar ratio of hydrogen/carbon monoxide, partial pressure of propylene, molar ratio of rhodium/TPPTS and concentration of rhodium catalyst on the initial rate of reaction were determined by margin and variance analysis. Several empirical rate equations were proposed to represent the experimental data. The kinetic parameters were evaluated and the activation energy was found in the range of 75 similar to 85 kJ/mol. The regioselectivity of hydroformylation was also determined and the molar ratio of normal/isomeric aldehyde varied from 3.9 to 56.1. 2002 Elsevier Science B.V. (C) All rights reserved. |
| Keyword | Propylene Hydroformylation Kinetics Orthogonal Experimental Design |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences ; Technology |
| URL | 查看原文 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Keyword | WATER-SOLUBLE CATALYSTS ; MECHANISM ; ETHYLENE |
| WOS Research Area | Chemistry ; Engineering |
| WOS Subject | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| WOS ID | WOS:000176407000014 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Version | 出版稿 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/5663 |
| Collection | 研究所（批量导入） |
| Affiliation | Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China |
| Recommended Citation GB/T 7714 | Yang, C,Mao, ZS,Wang, YF,et al. Kinetics of hydroformylation of propylene using RhCl(CO)(TPPTS)(2)/TPPTS complex catalyst in aqueous system[J]. CATALYSIS TODAY,2002,74(1-2):111-119. |
| APA | Yang, C,Mao, ZS,Wang, YF,&Chen, JY.(2002).Kinetics of hydroformylation of propylene using RhCl(CO)(TPPTS)(2)/TPPTS complex catalyst in aqueous system.CATALYSIS TODAY,74(1-2),111-119. |
| MLA | Yang, C,et al."Kinetics of hydroformylation of propylene using RhCl(CO)(TPPTS)(2)/TPPTS complex catalyst in aqueous system".CATALYSIS TODAY 74.1-2(2002):111-119. |
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| Kinetics of hydrofor（126KB） | 限制开放 | CC BY-NC-SA | Application Full Text | |||
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