CAS OpenIR  > 研究所(批量导入)
Isokinetic correlation analysis of the series of electrophilic substitution reactions of o-substituted phenylmercurials
Alternative TitleSci. China Ser. B-Chem.
Wang, YL; Wu, YJ
2001-04-01
Source PublicationSCIENCE IN CHINA SERIES B-CHEMISTRY
ISSN1006-9291
Volume44Issue:2Pages:182-190
AbstractIsokinetic relationships of the series of electrophilic substitution reactions of o-substituted phenylmercurials are studied, and the results show, for the first time! that isokinetic correlation analysis can reveal the dominant factor in the system of the reactions. The analysis of S(E)2 of o-substituted phenylmercuric chlorides indicates that the steric effect of o-substituents is the predominant factor when I-2 is used as electrophilic agent, however, the electronic effect of o-substituents would become the predominant factor when HCl is used as the electrophilic agent. In S(E)1 of o-substituted phenylmercuric chlorides, the results of the analysis display that the predominant factor is the field effects of o-substituents. The determination of predominant factors in those reactions would provide further scientific basis for those reaction mechanisms.; Isokinetic relationships of the series of electrophilic substitution reactions of o-substituted phenylmercurials are studied, and the results show, for the first time! that isokinetic correlation analysis can reveal the dominant factor in the system of the reactions. The analysis of S(E)2 of o-substituted phenylmercuric chlorides indicates that the steric effect of o-substituents is the predominant factor when I-2 is used as electrophilic agent, however, the electronic effect of o-substituents would become the predominant factor when HCl is used as the electrophilic agent. In S(E)1 of o-substituted phenylmercuric chlorides, the results of the analysis display that the predominant factor is the field effects of o-substituents. The determination of predominant factors in those reactions would provide further scientific basis for those reaction mechanisms.
KeywordIsokinetic Correlation Dominant Factor Electrophilic Substitution Arylmercurials
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
URL查看原文
Indexed BySCI
Language英语
WOS KeywordARYLMERCURIALS ; DIMERIZATION
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000168510600008
Citation statistics
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/5756
Collection研究所(批量导入)
Affiliation1.Chinese Acad Sci, Inst Chem Met, Natl Key Lab Biochem Engn, Beijing 100080, Peoples R China
2.Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
Recommended Citation
GB/T 7714
Wang, YL,Wu, YJ. Isokinetic correlation analysis of the series of electrophilic substitution reactions of o-substituted phenylmercurials[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2001,44(2):182-190.
APA Wang, YL,&Wu, YJ.(2001).Isokinetic correlation analysis of the series of electrophilic substitution reactions of o-substituted phenylmercurials.SCIENCE IN CHINA SERIES B-CHEMISTRY,44(2),182-190.
MLA Wang, YL,et al."Isokinetic correlation analysis of the series of electrophilic substitution reactions of o-substituted phenylmercurials".SCIENCE IN CHINA SERIES B-CHEMISTRY 44.2(2001):182-190.
Files in This Item:
File Name/Size DocType Version Access License
Isokineticcorrel_省略_(444KB) 限制开放CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Wang, YL]'s Articles
[Wu, YJ]'s Articles
Baidu academic
Similar articles in Baidu academic
[Wang, YL]'s Articles
[Wu, YJ]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Wang, YL]'s Articles
[Wu, YJ]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.