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Prediction of breakthrough curves for adsorption of lead(II) on activated carbon fibers in a fixed bed | |
Alternative Title | Carbon |
Xiu, GH; Li, P | |
2000 | |
Source Publication | CARBON
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ISSN | 0008-6223 |
Volume | 38Issue:7Pages:975-981 |
Abstract | The breakthrough curves were measured for the adsorption of aqueous Pb(NO3)(2) on activated carbon fibers (ACFs) in a fixed-bed adsorber. With the adsorption equilibrium constant and the intraparticle diffusivity determined from separate experiments in a batch tank, the breakthrough curves were predicted by the orthogonal collocation method. By the analysis of the effects of intraparticle and external mass transfer resistances as well as the axial dispersion on the breakthrough curves, the axial dispersion is confirmed to be the main parameter that controls the adsorption dynamics. Based on this analysis, the quasi-lognormal distribution approximation for linear isotherms and the constant pattern profiles solution for nonlinear isotherms were presented to predict the breakthrough curves for ACF fixed beds. In addition, the effluent pH curves were discussed with the changes of experimental conditions. (C) 2000 Elsevier Science Ltd. All rights reserved.; The breakthrough curves were measured for the adsorption of aqueous Pb(NO3)(2) on activated carbon fibers (ACFs) in a fixed-bed adsorber. With the adsorption equilibrium constant and the intraparticle diffusivity determined from separate experiments in a batch tank, the breakthrough curves were predicted by the orthogonal collocation method. By the analysis of the effects of intraparticle and external mass transfer resistances as well as the axial dispersion on the breakthrough curves, the axial dispersion is confirmed to be the main parameter that controls the adsorption dynamics. Based on this analysis, the quasi-lognormal distribution approximation for linear isotherms and the constant pattern profiles solution for nonlinear isotherms were presented to predict the breakthrough curves for ACF fixed beds. In addition, the effluent pH curves were discussed with the changes of experimental conditions. (C) 2000 Elsevier Science Ltd. All rights reserved. |
Keyword | Activated Carbon Fibers Transport Properties Adsorption Modelling |
Subtype | Article |
WOS Headings | Science & Technology ; Physical Sciences ; Technology |
URL | 查看原文 |
Indexed By | SCI |
Language | 英语 |
WOS Keyword | REMOVAL ; WATER ; APPROXIMATION |
WOS Research Area | Chemistry ; Materials Science |
WOS Subject | Chemistry, Physical ; Materials Science, Multidisciplinary |
WOS ID | WOS:000087261000002 |
Citation statistics | |
Document Type | 期刊论文 |
Version | 出版稿 |
Identifier | http://ir.ipe.ac.cn/handle/122111/6022 |
Collection | 研究所(批量导入) |
Affiliation | 1.Chinese Acad Sci, Inst Chem Met, Beijing 100080, Peoples R China 2.Shenyang Inst Chem Technol, Dept Chem Engn, Shenyang 110021, Peoples R China |
Recommended Citation GB/T 7714 | Xiu, GH,Li, P. Prediction of breakthrough curves for adsorption of lead(II) on activated carbon fibers in a fixed bed[J]. CARBON,2000,38(7):975-981. |
APA | Xiu, GH,&Li, P.(2000).Prediction of breakthrough curves for adsorption of lead(II) on activated carbon fibers in a fixed bed.CARBON,38(7),975-981. |
MLA | Xiu, GH,et al."Prediction of breakthrough curves for adsorption of lead(II) on activated carbon fibers in a fixed bed".CARBON 38.7(2000):975-981. |
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Prediction of breakt(128KB) | 限制开放 | CC BY-NC-SA | Application Full Text |
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