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Synthesis of symmetrical biaryls via rhodium catalyzed dimerization of arylmercurials and mechanism of the dimerization
Alternative TitleChem. Res. Chin. Univ.
Wang, YL; Wu, YJ
2000-05-01
Source PublicationCHEMICAL RESEARCH IN CHINESE UNIVERSITIES
ISSN1005-9040
Volume16Issue:2Pages:131-135
AbstractA series of symmetrical biaryls was synthesized from arylmercuric chlorides and biarylmercurials in the presence of [ClRh(CO)(2)](2) in hexamethylphosphoramide (HMPA). The mechanism of the [ClRh(CO)(2)](2) catalyzed dimerization of biarylmercurials was studied, and shown to be mainly intermolecular reaction.; A series of symmetrical biaryls was synthesized from arylmercuric chlorides and biarylmercurials in the presence of [ClRh(CO)(2)](2) in hexamethylphosphoramide (HMPA). The mechanism of the [ClRh(CO)(2)](2) catalyzed dimerization of biarylmercurials was studied, and shown to be mainly intermolecular reaction.
KeywordSymmetrical Biaryls Synthesis Arylmercurials Intermolecular Reaction
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
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Indexed BySCI
Language英语
WOS KeywordORGANOMERCURY COMPOUNDS
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000087467300007
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/6095
Collection研究所(批量导入)
Affiliation1.Chinese Acad Sci, Inst Chem Met, Natl Key Lab Biochem Engn, Beijing 100080, Peoples R China
2.Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
Recommended Citation
GB/T 7714
Wang, YL,Wu, YJ. Synthesis of symmetrical biaryls via rhodium catalyzed dimerization of arylmercurials and mechanism of the dimerization[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2000,16(2):131-135.
APA Wang, YL,&Wu, YJ.(2000).Synthesis of symmetrical biaryls via rhodium catalyzed dimerization of arylmercurials and mechanism of the dimerization.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,16(2),131-135.
MLA Wang, YL,et al."Synthesis of symmetrical biaryls via rhodium catalyzed dimerization of arylmercurials and mechanism of the dimerization".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 16.2(2000):131-135.
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