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Hydrothermal synthesis and structure of three novel open-framework lanthanide sulfate-oxalates
Li, Li1,2; Yu, Ranbo3; Wang, Dan1; Lai, Xiaoyong1; Mao, Dan1; Yang, Mei1; Wang, D
2010-07-01
Source PublicationINORGANIC CHEMISTRY COMMUNICATIONS
ISSN1387-7003
Volume13Issue:7Pages:831-833
AbstractThree novel hybrid open-framework lanthanide sulfate-oxalates, {[NH(4)][Ln(H(2)O)(SO(4))(C(2)O(4))]}(n) [Ln = Y (1), La (II), Sm (III)] have been synthesized via hydrothermal reaction, and characterized by single crystal X-ray diffraction, powder X-ray diffraction, infrared spectrophotometry, thermal gravimetric analysis and fluorescence analysis. These three compounds were isostructural, and all crystallized into the monoclinic system with space group of P2(1)/n. In their structures, LnO(8) dodecahedra, SO(4) tetrahedral and C(2)O(4) groups are linked to give rise to a three-dimensional open-framework, which contains two kinds of 12-membered ring channel systems running along the a and b axis, respectively. (C) 2010 Elsevier B.V. All rights reserved.
KeywordHydrothermal Synthesis Inorganic-organic Hybrid Material Open-framework Crystal Structure
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1016/j.inoche.2010.04.004
Indexed BySCI
Language英语
WOS KeywordCERIUM PHOSPHATE FLUORIDE ; CRYSTAL-STRUCTURE ; METAL SULFATES ; SOLVOTHERMAL SYNTHESIS ; ORGANIC FRAMEWORKS ; CHAINS ; ACID ; PR ; ND
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000279602100007
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/6123
Collection多相复杂系统国家重点实验室
Corresponding AuthorWang, D
Affiliation1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase & Complex Syst, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.Univ Sci & Technol Beijing, Dept Phys Chem, Beijing 100086, Peoples R China
Recommended Citation
GB/T 7714
Li, Li,Yu, Ranbo,Wang, Dan,et al. Hydrothermal synthesis and structure of three novel open-framework lanthanide sulfate-oxalates[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2010,13(7):831-833.
APA Li, Li.,Yu, Ranbo.,Wang, Dan.,Lai, Xiaoyong.,Mao, Dan.,...&Wang, D.(2010).Hydrothermal synthesis and structure of three novel open-framework lanthanide sulfate-oxalates.INORGANIC CHEMISTRY COMMUNICATIONS,13(7),831-833.
MLA Li, Li,et al."Hydrothermal synthesis and structure of three novel open-framework lanthanide sulfate-oxalates".INORGANIC CHEMISTRY COMMUNICATIONS 13.7(2010):831-833.
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