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Formation of cubic Cu mesocrystals by a solvothermal reaction
Cao, Yuebin1,2; Fan, Junmei1,2; Bai, Liuyang1,2; Hu, Peng1,2; Yang, Gang1,2; Yuan, Fangli1,2; Chen, Yunfa1,2; Yuan, FL
2010
Source PublicationCRYSTENGCOMM
ISSN1466-8033
Volume12Issue:11Pages:3894-3899
AbstractCubic Cu mesocrystals were prepared via a facile solvothermal reaction in a mixed solvent of glycerol-water. The microstructure of synthesized mesocrystals can be successfully controlled by adjusting the volume ratio of glycerol/water. The evolution of these cubic Cu mesocrystals was investigated and the mechanism was discussed. The oriented attachment process controls the initial stage in the formation of scabbled cubic Cu mesocrystals and then Ostwald ripening process contributes to the formation of the final Cu mesocrystals by shearing the scabbled mesocrystals. The influences of reaction temperature and NaOH concentration on the morphology of the synthesized mesocrystals were also investigated. Isotropic conductive adhesives (ICA), filled with cubic Cu mesocrystals, exhibit a low bulk resistivity, of about 5.21 x 10(-4) Omega cm.
KeywordOriented Attachment Calcium-carbonate Copper Nanowires Nonclassical Crystallization Silver Nanowires Growth-mechanism Shape Control Nanocrystals Route Morphology
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1039/c003554h
Indexed BySCI
Language英语
WOS KeywordORIENTED ATTACHMENT ; CALCIUM-CARBONATE ; COPPER NANOWIRES ; NONCLASSICAL CRYSTALLIZATION ; SILVER NANOWIRES ; GROWTH-MECHANISM ; SHAPE CONTROL ; NANOCRYSTALS ; ROUTE ; MORPHOLOGY
WOS Research AreaChemistry ; Crystallography
WOS SubjectChemistry, Multidisciplinary ; Crystallography
WOS IDWOS:000283315900091
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/6234
Collection多相复杂系统国家重点实验室
Corresponding AuthorYuan, FL
Affiliation1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Cao, Yuebin,Fan, Junmei,Bai, Liuyang,et al. Formation of cubic Cu mesocrystals by a solvothermal reaction[J]. CRYSTENGCOMM,2010,12(11):3894-3899.
APA Cao, Yuebin.,Fan, Junmei.,Bai, Liuyang.,Hu, Peng.,Yang, Gang.,...&Yuan, FL.(2010).Formation of cubic Cu mesocrystals by a solvothermal reaction.CRYSTENGCOMM,12(11),3894-3899.
MLA Cao, Yuebin,et al."Formation of cubic Cu mesocrystals by a solvothermal reaction".CRYSTENGCOMM 12.11(2010):3894-3899.
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