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Pd-0@Polyoxometalate Nanostructures as Green Electrocatalysts: Illustrative Example of Hydrogen Production
Biboum, Rosa N.1; Keita, Bineta1; Franger, Sylvain2; Njiki, Charles P. Nanseu1; Zhang, Guangjin3; Zhang, Jie4; Liu, Tianbo4; Mbomekalle, Israel-Martyr5; Nadjo, Louis1; Keita, B
2010
Source PublicationMATERIALS
ISSN1996-1944
Volume3Issue:1Pages:741-754
AbstractGreen-chemistry type procedures were used to synthesize Pd-0 nanostructures encapsulated by a vanadium-substituted Wells-Dawson-type polyoxometalate (Pd-0@POM). The cyclic voltammogram run with the Pd-0@POM-modified glassy carbon electrode shows well-defined waves, associated with Pd-0 nanostructures and the V-V/V-IV redox couple. The Pd-0@POM-modified electrode displayed remarkably reproducible cyclic voltammetry patterns. The hydrogen evolution reaction (HER) was selected as an illustrative example to test the electrocatalytic behavior of the electrode. The kinetic parameters of the HER show the high efficiency of the Pd-0@POM-modified electrode. This is the first example of electrochemical characterization of a modified electrode based on a vanado-tungstic POM and Pd-0 nanostructures.
KeywordGreen Chemistry Palladium Nanoparticles Nanostructures Vanadium-substituted Polyoxotungstate Self-assembly Hydrogen Evolution Reaction
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
DOI10.3390/ma3010741
Indexed BySCI
Language英语
WOS KeywordONE-STEP SYNTHESIS ; OXIDE FUEL-CELLS ; METAL NANOPARTICLES ; AQUEOUS-SOLUTION ; COLLOIDAL SOLUTIONS ; FACILE SYNTHESIS ; PALLADIUM ; EVOLUTION ; TRANSITION ; REDUCTION
WOS Research AreaMaterials Science
WOS SubjectMaterials Science, Multidisciplinary
WOS IDWOS:000298240100040
Citation statistics
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/6249
Collection湿法冶金清洁生产技术国家工程实验室
Corresponding AuthorKeita, B
Affiliation1.Univ Paris 11, CNRS, Chim Phys Lab, Grp Electrochim & Photoelectrochime,UMR 800, F-91405 Orsay, France
2.Univ Paris 11, CNRS, Lab Physicochim Etat Solide, ICMMO,UMR8182, F-91405 Orsay, France
3.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc Engn, Beijing 100190, Peoples R China
4.Lehigh Univ, Dept Chem, Bethlehem, PA 18015 USA
5.Univ Versailles St Quentin, Inst Lavoisier, UMR 8180, F-78035 Versailles, France
Recommended Citation
GB/T 7714
Biboum, Rosa N.,Keita, Bineta,Franger, Sylvain,et al. Pd-0@Polyoxometalate Nanostructures as Green Electrocatalysts: Illustrative Example of Hydrogen Production[J]. MATERIALS,2010,3(1):741-754.
APA Biboum, Rosa N..,Keita, Bineta.,Franger, Sylvain.,Njiki, Charles P. Nanseu.,Zhang, Guangjin.,...&Keita, B.(2010).Pd-0@Polyoxometalate Nanostructures as Green Electrocatalysts: Illustrative Example of Hydrogen Production.MATERIALS,3(1),741-754.
MLA Biboum, Rosa N.,et al."Pd-0@Polyoxometalate Nanostructures as Green Electrocatalysts: Illustrative Example of Hydrogen Production".MATERIALS 3.1(2010):741-754.
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