CAS OpenIR  > 湿法冶金清洁生产技术国家工程实验室
Water as an efficient medium for the synthesis of cyclic carbonate
Sun, Jian1,2; Ren, Junyi3; Zhang, Suojiang1; Cheng, Weiguo1; Zhang, SJ
2009-01-28
Source PublicationTETRAHEDRON LETTERS
ISSN0040-4039
Volume50Issue:4Pages:423-426
AbstractHerein, we report a novel method for the synthesis of cyclic carbonate in water. By tuning the amount of water, cycloaddition Of CO(2) to epoxide in aqueous medium leads to cyclic carbonates with moderate to excellent yields and high selectivities. In addition, the presence of water could remarkably improve the activity of ionic liquids by which the turnover frequency of the reaction is about 4-5 times higher in the presence than in the absence of water. The relationship between the higher catalytic reactivity and water was proposed. (c) 2008 Elsevier Ltd. All rights reserved.
KeywordWater Carbon Dioxide Ionic Liquid Cyclic Carbonate
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1016/j.tetlet.2008.11.034
Indexed BySCI ; CCR
Language英语
WOS KeywordCHEMICAL FIXATION ; IONIC LIQUIDS ; CATALYST SYSTEM ; COUPLING REACTIONS ; PROPYLENE-OXIDE ; SUPERCRITICAL CONDITIONS ; HOMOGENEOUS CATALYST ; STYRENE CARBONATE ; HIGHLY EFFICIENT ; ORGANIC-BASES
WOS Research AreaChemistry
WOS SubjectChemistry, Organic
WOS IDWOS:000263253500013
Citation statistics
Cited Times:175[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/6757
Collection湿法冶金清洁生产技术国家工程实验室
Corresponding AuthorZhang, SJ
Affiliation1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.Dalian Polytech Univ, Dalian 116034, Peoples R China
Recommended Citation
GB/T 7714
Sun, Jian,Ren, Junyi,Zhang, Suojiang,et al. Water as an efficient medium for the synthesis of cyclic carbonate[J]. TETRAHEDRON LETTERS,2009,50(4):423-426.
APA Sun, Jian,Ren, Junyi,Zhang, Suojiang,Cheng, Weiguo,&Zhang, SJ.(2009).Water as an efficient medium for the synthesis of cyclic carbonate.TETRAHEDRON LETTERS,50(4),423-426.
MLA Sun, Jian,et al."Water as an efficient medium for the synthesis of cyclic carbonate".TETRAHEDRON LETTERS 50.4(2009):423-426.
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