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Preparation and Characterization of Titanium Tetrachloride-Based Ionic Liquids
Gao, Lixia1,2; Wang, Lina1; Qi, Tao1; Chu, Jinglong1; Qu, Jingkui1; Gao, LX
2009
Source PublicationJOURNAL OF THE ELECTROCHEMICAL SOCIETY
ISSN0013-4651
Volume156Issue:3Pages:P49-P55
AbstractA series of TiCl(4)-based ionic liquids (ILs) was synthesized by mixing TiCl(4) with quaternary ammonium, pyridinium, and imidazolium chlorogenated salt, respectively. The structure and composition of the ILs were studied with Fourier transform ion cyclotron resonance mass spectrometry. IR, and Raman spectra. The primary anions of the TiCl(4)-based ILs were TiCl(9)(-) and TiCl(6)(2-), whose amounts were different by variation of the molar ratio of TiCl(4) to organic halogenated salt. The physical properties such as the phase transition behavior, surface tension, density, viscosity, and conductivity of these ILs were also investigated. Temperature-dependent viscocity and conductivity of the ILs followed the Vogel-Tammann-Fulcher equation, and the best-fit parameters had been estimated, together with the lienar fitting parameters for the density. The conductivity and viscosity of the TiCl(4)-based ILs were controlled by the ion mobility and the availability of voids with suitable dimensions. Hole theory could well explain the physicochemical properties of the TiCl(4)-based ILs. (c) 2008 The Electrochemical Society. [DOI: 10.1149/1.3046160] All rights reserved.
KeywordTemperature Molten-salt In-situ Stm Cobalt-aluminum Alloys Chloride Molten Electrical Conductivities Physical-properties Phase-transitions Raman-spectra Hole Theory C-13 Nmr
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1149/1.3046160
Indexed BySCI
Language英语
WOS KeywordTEMPERATURE MOLTEN-SALT ; IN-SITU STM ; COBALT-ALUMINUM ALLOYS ; CHLORIDE MOLTEN ; ELECTRICAL CONDUCTIVITIES ; PHYSICAL-PROPERTIES ; PHASE-TRANSITIONS ; RAMAN-SPECTRA ; HOLE THEORY ; C-13 NMR
WOS Research AreaElectrochemistry ; Materials Science
WOS SubjectElectrochemistry ; Materials Science, Coatings & Films
WOS IDWOS:000265837900073
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/6791
Collection湿法冶金清洁生产技术国家工程实验室
Corresponding AuthorGao, LX
Affiliation1.Chinese Acad Sci, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Gao, Lixia,Wang, Lina,Qi, Tao,et al. Preparation and Characterization of Titanium Tetrachloride-Based Ionic Liquids[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2009,156(3):P49-P55.
APA Gao, Lixia,Wang, Lina,Qi, Tao,Chu, Jinglong,Qu, Jingkui,&Gao, LX.(2009).Preparation and Characterization of Titanium Tetrachloride-Based Ionic Liquids.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,156(3),P49-P55.
MLA Gao, Lixia,et al."Preparation and Characterization of Titanium Tetrachloride-Based Ionic Liquids".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 156.3(2009):P49-P55.
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