| Preparation and Characterization of Titanium Tetrachloride-Based Ionic Liquids | |
| Gao, Lixia1,2; Wang, Lina1; Qi, Tao1; Chu, Jinglong1; Qu, Jingkui1; Gao, LX | |
| 2009 | |
| Source Publication | JOURNAL OF THE ELECTROCHEMICAL SOCIETY
 |
| ISSN | 0013-4651 |
| Volume | 156Issue:3Pages:P49-P55 |
| Abstract | A series of TiCl(4)-based ionic liquids (ILs) was synthesized by mixing TiCl(4) with quaternary ammonium, pyridinium, and imidazolium chlorogenated salt, respectively. The structure and composition of the ILs were studied with Fourier transform ion cyclotron resonance mass spectrometry. IR, and Raman spectra. The primary anions of the TiCl(4)-based ILs were TiCl(9)(-) and TiCl(6)(2-), whose amounts were different by variation of the molar ratio of TiCl(4) to organic halogenated salt. The physical properties such as the phase transition behavior, surface tension, density, viscosity, and conductivity of these ILs were also investigated. Temperature-dependent viscocity and conductivity of the ILs followed the Vogel-Tammann-Fulcher equation, and the best-fit parameters had been estimated, together with the lienar fitting parameters for the density. The conductivity and viscosity of the TiCl(4)-based ILs were controlled by the ion mobility and the availability of voids with suitable dimensions. Hole theory could well explain the physicochemical properties of the TiCl(4)-based ILs. (c) 2008 The Electrochemical Society. [DOI: 10.1149/1.3046160] All rights reserved. |
| Keyword | Temperature Molten-salt In-situ Stm Cobalt-aluminum Alloys Chloride Molten Electrical Conductivities Physical-properties Phase-transitions Raman-spectra Hole Theory C-13 Nmr |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences ; Technology |
| DOI | 10.1149/1.3046160 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Keyword | TEMPERATURE MOLTEN-SALT ; IN-SITU STM ; COBALT-ALUMINUM ALLOYS ; CHLORIDE MOLTEN ; ELECTRICAL CONDUCTIVITIES ; PHYSICAL-PROPERTIES ; PHASE-TRANSITIONS ; RAMAN-SPECTRA ; HOLE THEORY ; C-13 NMR |
| WOS Research Area | Electrochemistry ; Materials Science |
| WOS Subject | Electrochemistry ; Materials Science, Coatings & Films |
| WOS ID | WOS:000265837900073 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Version | 出版稿 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/6791 |
| Collection | 湿法冶金清洁生产技术国家工程实验室 |
| Corresponding Author | Gao, LX |
| Affiliation | 1.Chinese Acad Sci, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Gao, Lixia,Wang, Lina,Qi, Tao,et al. Preparation and Characterization of Titanium Tetrachloride-Based Ionic Liquids[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2009,156(3):P49-P55. |
| APA | Gao, Lixia,Wang, Lina,Qi, Tao,Chu, Jinglong,Qu, Jingkui,&Gao, LX.(2009).Preparation and Characterization of Titanium Tetrachloride-Based Ionic Liquids.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,156(3),P49-P55. |
| MLA | Gao, Lixia,et al."Preparation and Characterization of Titanium Tetrachloride-Based Ionic Liquids".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 156.3(2009):P49-P55. |
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| 20131211-259-复件 P49.（628KB） | 限制开放 | CC BY-NC-SA | Application Full Text | |||
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