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有机单硫代磷酸-三辛胺反协同萃取镉锌
张大力; 卢立柱; 柯家骏
2002
Source Publication稀有金属
Issue05Pages:351-355
Abstract研究了二 (2 乙基己基 )单硫代磷酸 (D2EHMTPA) 三辛胺 (TOA)混合萃取剂萃取镉锌的机理。电导滴定、红外和核磁共振谱以及等摩尔系列法等实验表明 ,D2EHMTPA与TOA混合形成离子缔合体 ,其萃取镉锌为反协同萃取 ,萃合物为CdA2 ·BHA和ZnA2 。萃取机理如下 :M2 ++ (2 +m)BHA(o) =MA2 ·mBHA(o) + 2B(o) + 2H+ (M2 + =Zn2 + 时 ,m =0 ;M2 + =Cd2 + 时 ,m =1)。
Keyword单硫代磷酸 三辛胺 反协同萃取
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/6919
Collection研究所(批量导入)
Recommended Citation
GB/T 7714
张大力,卢立柱,柯家骏. 有机单硫代磷酸-三辛胺反协同萃取镉锌[J]. 稀有金属,2002(05):351-355.
APA 张大力,卢立柱,&柯家骏.(2002).有机单硫代磷酸-三辛胺反协同萃取镉锌.稀有金属(05),351-355.
MLA 张大力,et al."有机单硫代磷酸-三辛胺反协同萃取镉锌".稀有金属 .05(2002):351-355.
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