Knowledge Management System Of Institute of process engineering,CAS
| Efficient fixation of CO2 into organic carbonates catalyzed by 2-hydroxymethyl-functionalized ionic liquids | |
| Alternative Title | RSC Adv. |
| Wang, Jin-Quan; Cheng, Wei-Guo; Sun, Jian; Shi, Tian-Yuan; Zhang, Xiang-Ping; Zhang, Suo-Jiang | |
| 2014 | |
| Source Publication | RSC ADVANCES
 |
| ISSN | 2046-2069 |
| Volume | 4Issue:5Pages:2360-2367 |
| Abstract | Several novel 2-hydroxymethyl-functionalized ILs act as the catalysts for synthesis of cyclic carbonates from CO2 and epoxides without the use of any co-catalysts or organic solvent. Moreover, the 2-hydroxymethyl-functionalized ILs were compatible with base, which combined with K2CO3 were used as effective catalytic system for green synthesis of dimethyl carbonate from CO2 via ethylene carbonate without catalyst separation. Additionally, the mechanistic details of the fixation of CO2 into cyclic carbonate catalyzed by 2-hydroxymethyl-functionalized ILs were also elucidated by density functional theory. The process reported here represents a simple, ecologically safer, cost-effective and energy-saving route to organic carbonates from CO2.; Several novel 2-hydroxymethyl-functionalized ILs act as the catalysts for synthesis of cyclic carbonates from CO2 and epoxides without the use of any co-catalysts or organic solvent. Moreover, the 2-hydroxymethyl-functionalized ILs were compatible with base, which combined with K2CO3 were used as effective catalytic system for green synthesis of dimethyl carbonate from CO2 via ethylene carbonate without catalyst separation. Additionally, the mechanistic details of the fixation of CO2 into cyclic carbonate catalyzed by 2-hydroxymethyl-functionalized ILs were also elucidated by density functional theory. The process reported here represents a simple, ecologically safer, cost-effective and energy-saving route to organic carbonates from CO2. |
| Keyword | Cyclic Carbonate Dimethyl Carbonate Highly Efficient Propylene-oxide Ethylene-oxide Dioxide Epoxides Cycloaddition Transformation Conversion |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1039/c3ra45918g |
| URL | 查看原文 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Keyword | CYCLIC CARBONATE ; DIMETHYL CARBONATE ; HIGHLY EFFICIENT ; PROPYLENE-OXIDE ; ETHYLENE-OXIDE ; DIOXIDE ; EPOXIDES ; CYCLOADDITION ; TRANSFORMATION ; CONVERSION |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000329035400038 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Version | 出版稿 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/8087 |
| Collection | 研究所（批量导入） |
| Affiliation | Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | Wang, Jin-Quan,Cheng, Wei-Guo,Sun, Jian,et al. Efficient fixation of CO2 into organic carbonates catalyzed by 2-hydroxymethyl-functionalized ionic liquids[J]. RSC ADVANCES,2014,4(5):2360-2367. |
| APA | Wang, Jin-Quan,Cheng, Wei-Guo,Sun, Jian,Shi, Tian-Yuan,Zhang, Xiang-Ping,&Zhang, Suo-Jiang.(2014).Efficient fixation of CO2 into organic carbonates catalyzed by 2-hydroxymethyl-functionalized ionic liquids.RSC ADVANCES,4(5),2360-2367. |
| MLA | Wang, Jin-Quan,et al."Efficient fixation of CO2 into organic carbonates catalyzed by 2-hydroxymethyl-functionalized ionic liquids".RSC ADVANCES 4.5(2014):2360-2367. |
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| File Name/Size | DocType | Version | Access | License | ||
| Efficient fixation o（539KB） | 限制开放 | CC BY-NC-SA | Application Full Text | |||
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