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Efficient fixation of CO2 into organic carbonates catalyzed by 2-hydroxymethyl-functionalized ionic liquids
Alternative TitleRSC Adv.
Wang, Jin-Quan; Cheng, Wei-Guo; Sun, Jian; Shi, Tian-Yuan; Zhang, Xiang-Ping; Zhang, Suo-Jiang
2014
Source PublicationRSC ADVANCES
ISSN2046-2069
Volume4Issue:5Pages:2360-2367
AbstractSeveral novel 2-hydroxymethyl-functionalized ILs act as the catalysts for synthesis of cyclic carbonates from CO2 and epoxides without the use of any co-catalysts or organic solvent. Moreover, the 2-hydroxymethyl-functionalized ILs were compatible with base, which combined with K2CO3 were used as effective catalytic system for green synthesis of dimethyl carbonate from CO2 via ethylene carbonate without catalyst separation. Additionally, the mechanistic details of the fixation of CO2 into cyclic carbonate catalyzed by 2-hydroxymethyl-functionalized ILs were also elucidated by density functional theory. The process reported here represents a simple, ecologically safer, cost-effective and energy-saving route to organic carbonates from CO2.; Several novel 2-hydroxymethyl-functionalized ILs act as the catalysts for synthesis of cyclic carbonates from CO2 and epoxides without the use of any co-catalysts or organic solvent. Moreover, the 2-hydroxymethyl-functionalized ILs were compatible with base, which combined with K2CO3 were used as effective catalytic system for green synthesis of dimethyl carbonate from CO2 via ethylene carbonate without catalyst separation. Additionally, the mechanistic details of the fixation of CO2 into cyclic carbonate catalyzed by 2-hydroxymethyl-functionalized ILs were also elucidated by density functional theory. The process reported here represents a simple, ecologically safer, cost-effective and energy-saving route to organic carbonates from CO2.
KeywordCyclic Carbonate Dimethyl Carbonate Highly Efficient Propylene-oxide Ethylene-oxide Dioxide Epoxides Cycloaddition Transformation Conversion
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1039/c3ra45918g
URL查看原文
Indexed BySCI
Language英语
WOS KeywordCYCLIC CARBONATE ; DIMETHYL CARBONATE ; HIGHLY EFFICIENT ; PROPYLENE-OXIDE ; ETHYLENE-OXIDE ; DIOXIDE ; EPOXIDES ; CYCLOADDITION ; TRANSFORMATION ; CONVERSION
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000329035400038
Citation statistics
Cited Times:76[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/8087
Collection研究所(批量导入)
AffiliationChinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wang, Jin-Quan,Cheng, Wei-Guo,Sun, Jian,et al. Efficient fixation of CO2 into organic carbonates catalyzed by 2-hydroxymethyl-functionalized ionic liquids[J]. RSC ADVANCES,2014,4(5):2360-2367.
APA Wang, Jin-Quan,Cheng, Wei-Guo,Sun, Jian,Shi, Tian-Yuan,Zhang, Xiang-Ping,&Zhang, Suo-Jiang.(2014).Efficient fixation of CO2 into organic carbonates catalyzed by 2-hydroxymethyl-functionalized ionic liquids.RSC ADVANCES,4(5),2360-2367.
MLA Wang, Jin-Quan,et al."Efficient fixation of CO2 into organic carbonates catalyzed by 2-hydroxymethyl-functionalized ionic liquids".RSC ADVANCES 4.5(2014):2360-2367.
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