CAS OpenIR  > 研究所(批量导入)
Ionic liquid clusters: structure, formation mechanism, and effect on the behavior of ionic liquids
Alternative TitlePhys. Chem. Chem. Phys.
Chen, Shimou1; Zhang, Suojiang1; Liu, Xiaomin1; Wang, Jinquan1; Wang, Jianji2; Dong, Kun1; Sun, Jian1; Xu, Baohua1
2014
Source PublicationPHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN1463-9076
Volume16Issue:13Pages:5893-5906
AbstractThe microstructure of ionic liquids (ILs) has attracted much attention due to their relevance in physiochemical properties and behavior of ILs. The existence of clusters (or microheterogeneous structure) is one of the main features for many ILs, which provides fundamental information for understanding the performance of ILs in their applications. This perspective concentrates on the recent progresses in IL clusters research. Firstly, we give a brief introduction on the structure of clusters in neat ILs and IL solutions. Secondly, the possible formation mechanism of the IL clusters is described. Then, the effects of the clusters on the physicochemical properties, interfacial properties, confined geometry and assembly processes of ILs are discussed. Finally, we address the associated challenges and prospects on the future study of IL clusters.; The microstructure of ionic liquids (ILs) has attracted much attention due to their relevance in physiochemical properties and behavior of ILs. The existence of clusters (or microheterogeneous structure) is one of the main features for many ILs, which provides fundamental information for understanding the performance of ILs in their applications. This perspective concentrates on the recent progresses in IL clusters research. Firstly, we give a brief introduction on the structure of clusters in neat ILs and IL solutions. Secondly, the possible formation mechanism of the IL clusters is described. Then, the effects of the clusters on the physicochemical properties, interfacial properties, confined geometry and assembly processes of ILs are discussed. Finally, we address the associated challenges and prospects on the future study of IL clusters.
KeywordRay Photoelectron-spectroscopy Molecular-dynamics Simulations Silica-derived Networks Alkyl Chain-length Room-temperature Aqueous-solution Micelle Formation Aggregation Behavior Nanostructural Organization Physicochemical Properties
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1039/c3cp53116c
URL查看原文
Indexed BySCI
Language英语
WOS KeywordRAY PHOTOELECTRON-SPECTROSCOPY ; MOLECULAR-DYNAMICS SIMULATIONS ; SILICA-DERIVED NETWORKS ; ALKYL CHAIN-LENGTH ; ROOM-TEMPERATURE ; AQUEOUS-SOLUTION ; MICELLE FORMATION ; AGGREGATION BEHAVIOR ; NANOSTRUCTURAL ORGANIZATION ; PHYSICOCHEMICAL PROPERTIES
WOS Research AreaChemistry ; Physics
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS IDWOS:000332474700001
Citation statistics
Cited Times:93[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/8132
Collection研究所(批量导入)
Affiliation1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China
2.Henan Normal Univ, Minist Educ, Key Lab Green Chem Media & React, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
Recommended Citation
GB/T 7714
Chen, Shimou,Zhang, Suojiang,Liu, Xiaomin,et al. Ionic liquid clusters: structure, formation mechanism, and effect on the behavior of ionic liquids[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2014,16(13):5893-5906.
APA Chen, Shimou.,Zhang, Suojiang.,Liu, Xiaomin.,Wang, Jinquan.,Wang, Jianji.,...&Xu, Baohua.(2014).Ionic liquid clusters: structure, formation mechanism, and effect on the behavior of ionic liquids.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,16(13),5893-5906.
MLA Chen, Shimou,et al."Ionic liquid clusters: structure, formation mechanism, and effect on the behavior of ionic liquids".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 16.13(2014):5893-5906.
Files in This Item:
File Name/Size DocType Version Access License
Ionic liquid cluster(3995KB) 限制开放CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Chen, Shimou]'s Articles
[Zhang, Suojiang]'s Articles
[Liu, Xiaomin]'s Articles
Baidu academic
Similar articles in Baidu academic
[Chen, Shimou]'s Articles
[Zhang, Suojiang]'s Articles
[Liu, Xiaomin]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Chen, Shimou]'s Articles
[Zhang, Suojiang]'s Articles
[Liu, Xiaomin]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.